浮选过程中金属离子对异极矿硫化的影响-中南大学学报.PDFVIP

第 48 卷第 7 期 中南大学学报( 自然科学版) Vol.48 No.7 2017 年 7 月 Journal of Central South University (Science and Technology) July 2017 DOI: 10.11817/j.issn.1672-7207.2017.07.001 浮选过程中金属离子对异极矿硫化的影响 张国范，张凤云 ( 中南大学 资源加工与生物工程学院，湖南 长沙，410083) 摘要：通过浮选试验、溶液化学计算、动电位和 XPS 测试研究硫化以及金属离子对异极矿浮选的影响。研究结果 表明：常温条件下黄药对异极矿以及硫化后的异极矿捕收能力都较差，硫化后添加金属离子可明显提高异极矿的 2+ 2+ 2+ − 回收率，且活化的由弱到强顺序为：Cu ，Zn 或 Pb 。HS 是硫化异极矿的有效成分，金属离子对异极矿的活化 能力和pH 区间与金属离子水解后的荷正电组分的浓度有关；Na2S 硫化过程中添加 Pb2+可使异极矿表面形成 PbS ， 有利于提高黄药的吸附量，从而强化了异极矿的硫化过程并提高了异极矿的回收率。 关键词：异极矿；硫化；金属离子；浮选；黄药 中图分类号：TD91 文献标志码：A 文章编号：1672−7207(2017)07−1689−08 Effect of metal ions on sulfiding flotation of hemimorphite ZHANG Guofan, ZHANG Fengyun (School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China) Abstract: The influences of sulfidization and metal ions on flotation of hemimorphite were studied through flotation tests, solution chemistry calculations, zeta potential measurement and XPS test. The results show that it is hard to collect hemimorphite well by using xanthate at normal temperature. Though Na2S can not improve the collection of hemimorphite, it can obviously make collection better by reconditioning with metal ions after sulfidization. The strength 2+ 2+ 2+ − of the activation sequence from small to big is: Cu , Zn or Pb . HS is the main composition. The activation ability and pH value of metal ions are related with t