细度对脱硫灰胶凝特性影响.docVIP

细度对脱硫灰胶凝特性影响 　　摘要：研究脱硫灰细度对脱硫灰性能的影响。结果表明：脱硫灰粉磨后，脱硫灰粒度分布优化，脱硫灰粒径减小、比表面积增大并且需水量比降低。脱硫灰颗粒的细化促进了脱硫灰自硬化、脱硫灰-水泥体系力学强度的提高。脱硫灰粉磨70min后，脱硫灰7d自硬化强度提高了231.5%，28d抗压强度提高了33.3%；脱硫灰-水泥体系28d抗压强度提高了43.3%。SEM照片表明，脱硫灰细化后，自硬化水化产物增多，结构更加密实；XRD图谱表明脱硫灰细化后促进了活性SiO2的溶出，消耗掉了更多的Ca(OH)2并生成更多的水化产物。 关键词：脱硫灰；细度；物理特性，力学强度；水化产物 中图分类号：TU528 文献标识码：A文章编号： Influence of fineness on cementitious properties of desulfurization ash Abstract：The fineness on the properties of desulfurization ash was investigated. The results showed that after the desulfurization ash grinded, desulfurization ash particle size distribution optimized, particle size decreased, the specific surface area increased and the water demand ratio reduced. The refinement of desulfurization ash particles promoted the self-harden strength and desulfurization ash-cement strength. After desulfurization ash was grinded for 70min, 7d self-harden strength of desulfurization ash increased by 231.5% and 28d compressive strength increased by 33.3%. The 28d compressive strength of desulfurization ash-cement system was increased by 43.3%. SEM photos showed that after desulfurization gray grinded, self-hardening hydration products amount increased, the structure was more dense; The XRD patterns showed that grinding promoted the dissolution of the active SiO2 and more of Ca(OH)2 was consumed and generated more hydration products. Keywords：Desulfurization ash; fineness; physical properties; mechanical strength; hydration product 1引言 流化床锅炉燃煤技术(Circulating Fluidized Bed Combustion, CFBC)是目前我国火电厂广泛使用的一种先进的洁净燃烧技术，它具有燃烧效率高、燃料适应性广和脱硫程度高等优点[1-2]。 流化床燃煤脱硫灰（CFBC脱硫灰）就是煤在流化床锅炉中燃烧后产生的，由于脱硫的最佳温度在850~900℃[3]，流化床锅炉燃烧的温度通常控制在这个温度范围，远低于粉煤炉1400℃的温度。通常采用炉内喷钙脱硫，固硫剂一般采用石灰石，生石灰等。为了提高脱硫效率，Ca与S的摩尔比通常要高于理论值，一般在2.5~3.0之间，甚至更高，所以脱硫灰渣的产量较大，因而大力发展脱硫灰综合利用技术，提高利用效率异常关键。 脱硫灰因其需水量较大、早期水化反应活性低等特点限制了其作为胶凝材料应用及推广，其中脱硫灰颗粒较大是导致脱硫灰这一特性的重要原因。因此本文立足于探究脱硫灰细度对脱硫灰物理及水化性能的影响规律，研究脱硫灰物理性能、力学特征及水化特性随脱硫灰细度的变化规律，达到最大限度应用脱硫灰的目的。 2 实验 2.1原材料 循环流化床脱硫灰来自湖北宜昌东阳光铝火力发电厂，水泥采用