凝固浴组成对NMMO法纤维素膜形貌的影响-高校化学工程学报.PDFVIP

21 3 No.3 Vol.21 2007 6 Journal of Chemical Engineering of Chinese Universities June 2007 1003-9015(2007)03-0398-06 NMMO , ( , 100084) NMMO NMMO TQ028.8 TQ352.79 A Influence of Coagulation Bath on Morphology of Cellulose Membranes Prepared by NMMO Method LÜ Yang-cheng, WU Ying-xin (Department of Chemical Engineering, State Key Lab of Chemical Engineering, Tsinghua University, Beijing 100084, China) Abstract: In order to realize the control on morphology of cellulose membrane used for separation, the cellulose membranes were prepared by NMMO method with using water, methanol, ethanol and their binary solution as coagulation bath. The morphology of surface and cross section of dry membrane were observed. The pore structure parameters of wet membrane were determined. By comparison, the process and mechanism of pore forming in dry membrane was suggested, and the relativity and influence factors of cellulose crystal size and average pore diameter in wet membrane was discussed. The results show that the morphology of dry membrane is varied with coagulation bath clearly, while the porosity of wet membrane is almost constant. The compact region in dry membrane can appear porous structure when swelling by water. These pores have virtual effect on the average pore diameter of wet membrane. Through changing the composition of coagulation bath, the microstructure of cellulose membrane at dry and wet environment can be adjusted separately or synergistically. Key words: cellulose membrane; NMMO; coagulation bath; morphology 1