氧化铑变色薄膜的制备及其电变色研究-上海有机化学研究所.PDF

2002 年第 60 卷 化 学 学 报 Vol. 60 , 2002 第 7 期 , 1203～1208 ACTA CHIMICA SINICA No. 7 , 1203 ～1208 氧化铑变色薄膜的制备及其电变色研究 王海红　　赵崇军　　严曼明　　江志裕 (复旦大学化学系 　上海 200433) 摘要 　采用溶胶 - 凝胶方法制备了氧化铑电致变色薄膜. 通过施加阴极或阳极电位 ,薄膜在碱性电解液中呈现从亮 ( ) ( ) 黄 还原态 到深绿 氧化态 的可逆颜色变化 ,而且可达到上千次循环而性能不变. 采用 XRD , SEM , TG, DTA , UV V , FTIR 和循环伏安等技术对薄膜的晶态、形貌、热处理过程和电变色过程进行了研究. 得出 100 ℃处理的膜内含有 一定量的结晶水 ,其性能最好. 对薄膜的电致变色性能如 :着色效率、响应时间及循环寿命、开路记忆等进行了测试 , 并讨论了氧化铑薄膜电变色的反应机理. 关键词 　溶胶 - 凝胶法 ,氧化铑薄膜 , 电致变色 Preparation of Rhodium Oxide Films and Its Electrochromic Study WANG, HaiHong 　　ZHAO , ChongJun 　　YAN , ManMing 　　J IANG, ZhiYu ( Department of Chemistry , Fudan University , Shanghai 200433) Abstract 　Electrochromic rhodium oxide films prepared by solgel method exhibited reversible twocolor (bright yellow at reduction and dark green at oxidation) electrochromic behavior in alkaline solution with good cycle stability. The XRD , SEM , TG, DTA , UVV , FTIR and voltammetry methods were used to study the structure and electrochromic properties of the films. It was found that the amorphous bright yellow rhodium oxide film formed via a heat treatment at 100 ℃presented excellent electrochromic characteristics. Its electrochromic properties such as coloration efficiency , response time , cycle stability and open circuit memory were determined and a possible coloration mechanism of the rhodium oxide film was discussed. Keywords 　solgel method , rhodium oxide film , electrochromism