多次烧结对钨铜合金组织与性能的影响.pdfVIP

第 35 卷第 4 期 粉末冶金技术 Vol. 35, No. 4 2017 年 8 月 Powder Metallurgy Technology August 2017 多次烧结对钨铜合金组织与性能的影响  寸敏敏，陈文革 ，颜国君，张飞奇，高红梅 西安理工大学材料科学与工程学院，西安 710048 通信作者, E-mail: wgchen001@263.net 摘 要 对熔渗法制备的钨铜合金（CuW80 ）分别进行了 3、6、9 次烧结。采用金相显微镜、扫描电子显微镜、X 射线衍射 仪、压汞仪等表征手段，研究了烧结次数对 CuW80 合金组织和性能的影响。结果表明：随着烧结次数的增加，CuW80 合金 中钨颗粒直径逐渐增大并连接，铜相分布更加均匀，多次烧结未见新相生成；经过3 次烧结后，试样孔隙率由最初的 0.5185% 变为 2.0516% ，孔径增加主要集中在 0.5～3 μm 范围内，但 9 次烧结后试样的孔隙率大大降低；合金硬度由烧结前的 HB 204 变化至烧结后的 HB 188 ；试样电导率由25.06 mS/m 降低至21.92 mS/m ；合金密度较烧结前降低了 1.2%。 关键词 钨铜合金；烧结；孔隙率；组织；性能 分类号 TG142.71 Influence of multiple sintering on microstructure and properties of W–Cu alloy CUN Min-min, CHEN Wen-ge, YAN Guo-jun, ZHANG Fei-qi, GAO Hong-mei School of Materials Science and Engineering, Xi’an University of Technology, Xi’an 710048, China Corresponding author, E-mail: wgchen001@263.net ABSTRACT Tungsten–copper alloys (CuW80) prepared by infiltration sintering technology were sintered for 3, 6, 9 times. The microstructure and properties during sintering process were characterized by optical microscopy (OM), scanning electron microscopy (SEM), X-ray diffraction (XRD), and mercury porosimetry. The results show that, with the increase of sintering number, the particle size of tungsten phase increases, the distribution of copper phase is more uniform between W skeleton, and there is no new phase found in the CuW80 alloy after the multiple sintering. The porosity of the CuW80 alloy increases from 0.5185% to 2.0516% with the pore diameter in 0.5~3 μm after 3 times sintering, however, the porosity of the CuW80 alloy after 9 times sintering greatly reduced. The hardness and conductivity of CuW80 alloy are HB 204 and 25.06 mS/m, respectively, which are reduced to HB 188 and 21.92 mS/m after