浸水养护下混合水泥浆体孔溶液pH值对钢筋锈蚀的影响.PDFVIP

第43 卷第2 期 硅 酸 盐 学 报 Vol. 43 ，No. 2 2 0 1 5 年 2 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY Febuary ，2015 DOI ：10.14062/j.issn.0454-5648.2015.02.04 浸水养护下混合水泥浆体孔溶液pH 值对钢筋锈蚀的影响 王培铭，庞 敏，刘贤萍 (1. 同济大学材料科学与工程学院，上海201804; 2. 先进土木工程材料教育部重点实验室，上海201804) 摘 要：研究了粉煤灰和矿渣粉不同掺量时对后期水泥浆体孔溶液pH 值的影响，采用金属腐蚀原理- Pourbaix 图法分析了混 合水泥砂浆中钢筋锈蚀现象，探讨了浸水养护下浆体孔溶液pH 值与钢筋锈蚀的关系。结果表明：水泥浆体孔溶液pH 值随 粉煤灰掺量增加而降低，当掺量为90%时，730 d 浆体孔溶液pH 值可降至8.5 左右；矿渣粉水泥的浆体孔溶液pH 值均保持 在12 以上；浆体孔溶液pH 值低于12.2 时，钢筋就会发生锈蚀，降至9 以下时，钢筋锈蚀严重。 关键词：混合水泥；粉煤灰；矿渣粉；孔溶液pH 值；钢筋锈蚀；浸水养护 中图分类号：TU528 文献标志码：A 文章编号：0454–5648(2015)02–0152–07 网络出版时间： 网络出版地址： Effect of pH value of Pore Solution and on Corrosion-resistance of Steel Bar in Blended Cement Mortar under Water Curing Condition WANG Peiming, PANG Min, LIU Xianping (1. School of Materials Science and Engineering, Tongji University, Shanghai 201804; 2. Key Laboratory of Advanced Civil Engineering Material of Ministry of Education, Tongji University, Shanghai 201804, China) Abstract: The effect of contents of fly ash and slag on the pH value of the cement paste pore solution was investigated. The corrosion phenomenon of different alkalinities cement mortars under water curing condition was analyzed based on the principles of electrochemistry of corrosion-pourbaix figure. The correlation between the pH value and corrosion-resistance was discussed. The results show that the pH value of fly ash cement paste pore solution reduces with the increase of fly ash content, when the content of fly ash in blended cement is up to 90%, the pH value drops to 8.5. When the pH value is 12.2, the steel in mortar corrodes slightly. When the pH value of the