粉煤灰-石灰-二水石膏胶凝材料的体积稳定性及水化产物的性能 volume stability of fly ash-lime-gypsum binder and its hydration products.pdfVIP

文章编号：1007-046X(2010)01-0008-03 实验研究 粉煤灰－石灰－二水石膏胶凝材料的体积稳定性及水化产物的性能 Volume Stability of Fly Ash-Lime-Gypsum Binder and Its Hydration Products 1,2 2 2 周万良 ，詹炳根 ，龙靖华 （1.武汉大学水利水电学院 , 武汉 430072；2.合肥工业大学土木与水利工程学院,合肥 230009） 摘 用雷氏夹法对粉煤灰-石灰-二水石膏胶凝材料（要： FLD）的体积稳定性进行了研究，用 SEM 和XRD 对FLD 的水化 形貌和数量变化规律进行了产物 研究。FLD 中SO 含量为2.33％ 时体积稳定性良好，而SO 含量大于 4.65％ 时体 3 3 积稳定性差。在 FLD 中，随龄期增加，钙矾石数量不断增加，CaSO ·2H O 和 Ca（OH） 数量不断减少。配比为 4 2 2 粉煤灰：石灰：二水石膏＝65:25:10 的FLD 到420 d 龄期时仍在进行着粉煤灰的水化反应，还有钙矾石生成。FLD 矾石为典型的针状晶体，水化硅酸钙凝胶为无定形物质。中钙 FLD 体积稳定性差的原因是石膏含量过多，硬化后在 龄期内针状钙矾石晶体不断很长 产生。 关键词： 粉煤灰－石灰－二水石膏；胶凝材料；体积稳定性；水化产物 + + 中图分类号：TQ177.271 TQ172.44 文献标识码：A Abstract：In this paper，FLDs volume stability was studied with Le Chatelier apparatus, and the morphology and quantitative change law of hydration products of FLD were also investigated with SEM and XRD．When content of SO is less than 2.33% 3 or more than 4.65%，FLD shows a good or a poor volume stability respectively．In FLD，the amount of ettringite continuously increases and the quantity of CaSO ·2H O and Ca(OH) incessantly decreases with increase of curing age．Even at 420 day 4 2 2 curing age, the hydration reactions of fly ash still occur in FLD with mix proportion of 65：25：10(fly ash :lime:digypsum)， with ettringite produced.