二苯甲酮类聚乙二醇基水溶型紫外线吸收剂的合成-高校化学工程学报.pdfVIP

21 5 No.5 Vol.21 2007 10 Journal of Chemical Engineering of Chinese Universities Oct. 2007 1003-9015(2007)05-0891-05 , , , , , ( , 116012) 2,4-(UV-0)2--4-(2H4CBP) α- 1 (FT-IR)(UV)( H-NMR)(PEGC(MW)) PEG (MW) 1540 6.87 243 nm290 nm 322 nm PEG2000-g-(UV-0) PEG1540-g-(UV-0) 290 nm 2 2 17899.7 L⋅mol− 1⋅cm− 117073.6 L⋅mol− 1⋅cm− 1 2,4 - TQ610.491 A Synthesis and Characteristic of Water-Soluble Ultraviolet Absorbers Containing Benzophenone and Polyethyleneglycol Groups YU Shu-juan, ZHENG Yu-bin, YAN Li, SHANG Hong-zhou, LIANG Jue, CUI Guan-feng (Department of Polymer Materials, Dalian University of Technology, Dalian 116012, China) Abstract: 2-hydroxy-4-chloroacetate benzophenone was synthesized by 2,4-dihydoxybenzophenone (UV-0) and chloracetyl chloride, then a series of polyethyleneglycol based novel water-soluble ultraviolet absorbers were synthesized via the reaction of active a-chlorine in chloroacetate and polyethleneglycol sodium with different molecular weights. The products of water-soluble ultraviolet absorbers containing benzophenone and polyethyleneglycol with different molecular weights (PEG(M )-(UV-0) ) were characterized by FT-IR, UV and W 2 1H-NMR spectra. The effect of polyethyleneglycol with different molecular weights on the water-solubility of the products was also studied, and the photostabilities of the