基于导电油墨Cu-Ag复合结构的制备于性能大学论文.docxVIP

毕业论文题目：基于导电油墨Cu-Ag复合结构的制备及性能研究学院：化学化工学院专业：化学工程与工艺毕业年限： 2015 学生姓名：欧阳琼林学号： 20117302233 指导教师：唐小华中文摘要新时代对电子印刷技术的要求，使人们越来越将目光投向金属纳米导电油墨。几十年来，国内外研究的重点是银墨，其电阻率小，抗氧化性好，经久耐用，但其价格昂贵限制了它们在工业上的大规模推广。另一方面，铜墨的电阻率也很小，而且价格低廉，但铜墨的抗氧化能力差，不能长久保持其优异性能。为结合银墨和铜墨的优点，相互弥补二者的不足，本文用连续还原法，制备了在一缩二乙二醇溶液中分散较好的Cu-Ag复合结构纳米颗粒。方法为：先用抗坏血酸还原氢氧化铜，得到纳米铜颗粒，再与AgNO3溶液反应制备Cu-Ag纳米片/颗粒。通过扫描电镜（SEM）、X-射线衍射仪（XRD）、X射线能谱仪（EDX）、紫外吸收光谱（UV-vis）等的表征证明得到了Cu-Ag复合结构的纳米颗粒。以所制备的Cu-Ag纳米片/颗粒作为导电填料，加入相应添加剂配制出了导电油墨。通过丝网印刷的方法，将油墨印刷于柔性的聚酰亚胺基底上。在300℃氮气为保护气氛条件下，烧结90min得到导电图案。通过多功能电阻仪测电阻证明其导电性很好。基于导电性好、抗氧化性强和成本低廉这些优点，铜银复合导电油墨有望在工业上大规模推广。关键字：金属导电油墨复合结构纳米颗粒/片连续还原法抗氧化能力成本低廉AbstrcatWith the improved requirement of printed electronics technology,more and more attention has been paid to metallic nanoparticle conductive ink.During the past decades, the research has focus on sliver ink,which possess the properties of low electrical resistivity and excellent antioxidation ability,but the high cost restrict its large-scale application in industry. On the other hand,the copper ink also has low resistivity with significant lower expenditure compared to silver ink, yet the poverty of antioxidant makes it difficult on keeping its splendid properties. To unite the advantages of both sides and offset the shortcomings, Cu-Ag nanoparticles/nanoflakes owing the composite structurewith good dispersion in diethylene glycol via successive reduction were prepared. Specific process is as follows: Firstly,copper hydroxide wasreduced withL-ascorbic through polyols process to obtain Cunanoparticles.Then silver nitratereactedwithCu nanoparticlesto prepare Cu-Ag nanoparticles/nanoflakes. Characterizations byfield-emission scanning electron microscope(SEM),X-ray diffraction(XRD),energy dispersive X-ray spectroscopy(EDX) and UV-vis absorption spectroscopy have been carried out, results prove the product to beCu-Ag nanoparticle/nanoflakes. Conductive ink were prepared using the Cu-Ag nanoparticles/