先驱体转化法制备sioc多孔木质陶瓷-硅酸盐学报.pdfVIP

40 7 983 40 7 Vol. 40No. 7 2 0 1 2 7 JOURNAL OF THE CHINESE CERAMIC SOCIETY J u l y 2 0 1 2 SiOC ( 212013) SiOC X SiOC α- SiOSiORSiCC=C CH α-Ar SiOC 2 O2 1200 1h (0.03 Ω·cm) TB383 A 0454–5648(2012)07–0983–05 2012–07–03 14:54:47 /kcms/detail/11.2310.TQ1454.201207.983_011.html Preparation of Porous SiOC Woodceramics by Polymer Precursor Conversion PAN Jianmei YAN XuehuaCHENG XiaonongZHANG ChenghuaXU Guifang (School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu, China) Abstract: The porous SiOC woodceramics were prepared via sintering of a fir powder impregnated with a polymeric precursor (sili- con resin) at various sintering temperatures and holding time. The products were characterizated by X-ray diffraction, scanning elec- tron microscopy, Fourier transformation infrared spectroscopy and thermogravimetric analysis, respectively. The electrical property of the samples was investigated using a four-point probe method. The results indicate that the samples are mainly composed of SiOC glasses, α-quartz and free carbon. There mainly exist SiO bonds, SiOR bonds, SiC bonds, C=C bonds and CH bonds in the 2 chemical structures. The α-quartz particles appear spherical shape and are distributed on the surface of the porous structures. The samples exhibit superior thermal stability in Ar atmosphere. However, the samples show great mass loss in O2 atmosphere due to the oxidation reaction of the SiOC glasses and free carbon. The sample possesses a lower volume resistivity (0.03 Ω·cm) at 1 200 for 1 h.