阳极溶出伏安法水体镉污染快速测定方法研究.PDFVIP

第41卷第2期 中国测试 Vol.41 No.2 2015年2月 CHINA MEASUREMENT TEST February，2015 doi院10.11857/j.issn.1674-5124.2015.02.009 阳极溶出伏安法水体镉污染快速测定方法研究 刀 谞袁 张霖琳袁 滕恩江袁 吕怡兵袁 薛荔栋袁 高愈霄 （中国环境监测总站，北京 100012） 摘 要院建立一种快速测定水体中镉、铅、汞、砷的阳极溶出伏安法。对现场快速测定影响因素进行探讨，并主要对镉 的检出限、精密度和准确度进行研究，将该方法运用到广西龙江镉污染事故应急监测中，并与多种其他方法进行比 对。结果表明：该方法运用最优温度为5耀40益，水样最佳pH范围为4耀9。便携式阳极溶出伏安法测定污染水样中的 镉，检出限为0.1滋g/L，加标回收率在80%耀110%间；在实际样品质量浓度在2耀110滋g/L范围内准确度均满足要求，实 际样品测定精密度2%耀5%；与在线监测结果的相对偏差臆4%，与石墨炉原子吸收测定结果相对偏差臆1%。该方法稳 定、快速，灵敏度高，准确度好，可广泛用于重金属污染事故应急监测。 关键词院水环境；阳极溶出伏安法；镉；应急监测 文献标志码院A 文章编号院1674-5124渊2015冤02-0034-04 Study and application in determination of cadmium by portable anodic stripping voltammetry DAO Xu，ZHANG Linlin，TENG Enjiang，L譈 Yibing，XUE Lidong，GAO Yuxiao （China National Environmental Monitoring Centre，Beijing 100012，China） Abstract: A portable anodic stripping voltammetry method was established for heavy metal determining. After studying the factor which influence rapid determination including detection limit，precision and accuracy，the method was applied to Longjiang river cadmium pollution emergency monitoring and compared with other methods. The results show that the optimal temperature for portable anodic stripping voltammetry determination of cadmium in contaminated water samples is 5益 to 40益，the detection limit is 0.1滋g/L，the recovery rate is 80%耀110% in the actual sample，concentration of 2 滋g/L to 110滋g/L within the accuracy requirements，the actual precision of sample determination is from 2% to 5% ，and online monitoring vehicle determined the outcome of the relative deviation is less than 4%