一种主侧链均含偶氮基团的聚合物合成与性能研究-中国科技论文在线.PDF

第4卷 第6期 2009 年 6 月 中国科技论文在线 Sciencepaper Online 413 一种主侧链均含偶氮基团的聚合物 合成与性能研究 王东瑞，王晓工 （清华大学化学工程系高分子研究所，北京 100084 ） 摘 要：偶氮聚合物在光信息存储、光电通讯等方面具有巨大的应用潜力，开发新类型的偶氮聚合物，并研究其结 构-性能关系具有重要的理论意义和应用价值。设计并合成了一种新型的主侧链均含偶氮生色团的聚合物，首先通过 4,4’-二羟基偶氮苯与N,N-二溴乙基苯胺之间的Williamson反应缩聚得到主链含偶氮苯基团的先驱聚合物，再通过重氮 偶合反应得到目标产物，并利用核磁共振、红外光谱、紫外可见光谱、热分析等手段确认了所制备聚合物的结构。对 聚合物膜的光加工实验表明，主链含有偶氮生色团的先驱聚合物不能形成明显的表面起伏光栅，而在相同实验条件下， 主侧链均含偶氮苯基团的偶氮聚合物可光加工形成规整的表面起伏光栅。 关键词：材料学；偶氮聚合物；合成；表面起伏光栅 中图分类号：O631 文献标识码：A 文章编号：1673－7180(2009)06 －0413 －5 Synthesis of novel azo polymer containing azobenzene groups both on main-chain and side-chain Wang Dongrui ，Wang Xiaogong (Department of Chemical Engineering, Tsinghua University, Beijing 100084, China) Abstract: Azo polymers have attracted increasing interest in fundamental and application research for their promising use in many fields such as information storage. In this paper, a novel azo polymer containing azo chromophores both on main-chain and side-chain was prepared through a scheme that combined Williamson reaction and azo-coupling reaction. First, the precursor polymer with azobenzene groups on main-chain was obtained by condensation polymerization between 4,4’-dihydroxyazobenzene and N,N-(2-bromoethyl)aniline through Williamson reaction. Then the azo polymer containing azobenzene groups both on main-chain and side-chain was prepared through an azo-coupling reaction between the precursor polymer and the diazonium salt of 4-nitroaniline. The polymers obtained were characterized by using various methods including 1 H-NMR, FT-IR, UV-vis and DSC. The polymer containing