大型发电机主绝缘老化的热分析研究.PDF

第23 卷 第7 期 中 国 电 机 工 程 学 报 Vol.23 No.7 Jul.2003 2003 年7 月 Proceedings of the CSEE ©2003 Chin.Soc.for Elec.Eng. 文章编号：0258-8013 （2003 ）07-0099-03 中图分类号：TM85 文献标识码：A 学科分类号：470·4024 大型发电机主绝缘老化的热分析研究 鲍棋铭，高乃奎，马小芹，张 亮，谢恒堃 （西安交通大学电力设备电气绝缘国家重点实验室，陕西西安 710049） STUDY ON THE AGING OF STATOR INSULATION OF LARGE GENERATORS USING THERMOANALYSIS BAO Qi-ming, GAO Nai-kui, MA Xiao-qin, ZHANG Liang, XIE Heng-kun （State Key Laboratory of Electrical Insulation for Power Equipment, Xi’an Jiaotong University, Xi’an 710049, China ） ABSTRACT: The aging of stator insulation of large generators 1 引言 has great relation with appearance and development of micro 大型发电机定子主绝缘在长期的运行过程中， defects inside the insulation ,and deterioration of epoxy. In this 受到电、热、机械和环境因素的联合作用，其性能 paper, Thermogravimetry (TG) and Differential Scanning Calorimeter (DSC) analysis are applied to the study on the 将逐渐变坏，并最终导致绝缘击穿。由于环氧-云母 aging of stator insulation of large generators. The results show 主绝缘体系在大型发电机运行过程中老化的复杂 that, compared with that of the sound parts, epoxy content and 性，目前，国际上在老化机理方面的研究还刚开始， starting oxidation temperature of the defective parts presented 尚未形成一个可以被大家广为接受的较为成熟的理 much more remarkable changes in its physical and chemical 论。在近年来的研究中，国内外的学者逐渐开始认 performance. In detail, its content and starting-temperature of 识到：老化与主绝缘内部微观缺陷的产生和发展以 oxidation decreased obviously; furthermore, its [1-2] 及环氧劣化有着极为密切的关系 。但令人遗憾的 decomposition-activation energy E of epoxy in the defective