含硼铁精矿回转窑直接还原-电炉熔分工艺研究.pdfVIP

含硼铁精矿回转窑直接还原- 电炉熔分工艺研究 ·1 · 含硼铁精矿回转窑直接还原- 电炉熔分工艺研究 赵嘉琦 付小佼 王 峥 柳政根 储满生1 （东北大学材料与冶金学院，辽宁沈阳 110819 ） 摘 要 硼铁矿是我国重要的硼资源，但该矿结构、成分复杂，综合利用难度大，至今未实现合理的综合开发利用。 硼铁矿经选矿完成硼铁的第一级分离之后，含硼铁精矿中的硼约占原矿硼总量的25%～30%，含硼铁精矿的高效利 用是硼铁矿综合利用的重要环节。实验室条件下对含硼铁精矿煤基回转窑直接还原-电热熔分工艺进行了研究。实 验结果表明：含硼铁精矿是优良的造球原料，在 1190℃焙烧20min 后，成品球团抗压强度达到2000N 以上，可满 足回转窑直接还原的要求；以非焦煤为还原剂，在950℃下还原150min 即可得到金属化率超过90%的直接还原铁， 满足电炉熔分的要求；在高温下进行电热熔分，渣铁分离效果较好，实现硼铁高效分离，其中富硼渣中B2O3 含量 达到 22.29%，活性达到 86.62%，是一步法生产硼酸的优良原料。含硼铁精矿回转窑直接还原-电热熔分可以实现 硼铁高效分离。 关键词 含硼铁精矿，直接还原，回转窑，电炉熔分 Study on the Process Utilizing Boron-bearing Iron Concentrate on Rotary Kiln Direct Reduction and Electric Furnace Smelting Separation Zhao Jiaqi, Fu Xiaojiao, Wang Zheng, Liu Zhenggen, Chu Mansheng (School of Materials Metallurgy, Northeastern University, Shenyang 110819, China) Abstract In this work, oxide pellet was prepared from boron-bearing iron concentrate. The process that the boron-bearing iron concentrate was directly reduced and separated by rotary kiln and electric furnace smelting, respectively, was studied. The results showed that boron-bearing iron concentrate pelletization can fully meet the requirements of the rotary kiln direct reduction process. After boasting at 1190 ℃ for 20min, the compressive strength of the finished pellet is higher than 2000N. Using non coking coal as reducing agent and selecting 950 ℃ as the reduction temperature, the time needs to reduce 90% of the boron-bearing iron concentrate was below 150min, which completely meets the requirements of the electric furnace smelting separation. Boron and iron can be efficiently separated by electric furnace at high temperature. The activity and the mass fraction of B O in the slag can reach 8