煅烧系统压强对石灰活性及微观结构的影响.pdfVIP

煅烧系统压强对石灰活性及微观结构的影响 ·1 · 煅烧系统压强对石灰活性及微观结构的影响 1 1 1,2 2 郝素菊 蒋武锋 张玉柱 郝华强 （1. 华北理工大学冶金与能源学院，河北唐山 063009 ； 2. 东北大学材料与冶金学院，辽宁沈阳 110819 ） 摘 要 石灰广泛应用于烧结和炼钢等工艺中，其活性直接影响生产效率和产品质量。本研究在高压电炉中煅烧石 灰石制备了活性石灰，采用酸碱滴定法测定了石灰的活性度，采用场发射扫描电镜（FE-SEM ）对活性石灰的形貌 进行了表征，详细研究了系统绝对压强对石灰活性度、CaO 晶粒大小及孔隙结构的影响。结果表明：高压条件下制 备的活性石灰，活性度较高，CaO 晶粒较大，孔隙也增大，并且呈层状结构。对于反应产物体积膨胀的石灰消化反 应，反应速率不仅与晶粒大小有关，而且与孔隙结构有关，大孔道的存在和层状结构有利于石灰消化反应的进行。 关键词 压强，活性石灰，活性度，微观孔隙结构，晶粒 Effect of Pressure on Lime’s Activity and Micro Structure 1 1 1,2 2 Hao Suju , Jiang Wufeng , Zhang Yuzhu , Hao Huaqiang (1. College of Metallurgy Energy, North China University of Science and Technology, Tangshan Hebei 063009, China; 2. School of Materials and Metallurgy, Northeastern University, Shenyang Liaoning 110819, China) Abstract Lime was extensively employed in metallurgical production, has significant influence on sintering and steelmaking process. The activity of lime directly affects the production efficiency and product quality. In this paper, lime was prepared by calcimining limestone in a high-pressure electric furnace. The activity of lime was determined by acid-base titration. The morphology of lime was characterized by Field Emission Scanning Electron Microscopy (FE-SEM). Influence of pressure on the activity of lime, size of CaO grain and pore structure were finely studied. The results indicate that the reaction ratio is related to both grain size of CaO and the micro pore structure when investigated the volume expansion of reaction product in lime s