氧化石墨烯的可控还原及表征研究开发.pdfVIP

化 工 进 展 2015 年第 34 卷第 9 期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·3383 · 研究开发 氧化石墨烯的可控还原及表征 赵静，张红 （上海工程技术大学化学化工学院，上海 201620 ） 摘要：采用 Hummers 修正法制备氧化石墨烯（GO ），用壳聚糖（CS ）作为“绿色”无毒还原剂，以反应温度和 反应时间来控制氧化石墨烯的还原程度。用红外光谱、紫外可见吸收光谱、拉曼光谱和 X 射线衍射等多种表征 手段研究不同还原程度的还原氧化石墨烯的结构与性能。结果表明，改变温度不能有效地控制氧化石墨烯的还 原程度；在 50 ℃低温环境下，控制反应时间可以得到不同还原程度的还原氧化石墨烯，为进一步研究不同还原 程度还原氧化石墨烯的非线性光学性质奠定了基础。 关键词：氧化石墨烯；石墨烯；可控还原 中图分类号：O 613.71 文献标志码：A 文章编号：1000 –6613 （2015 ）09 –3383 –05 DOI ：10.16085/j.issn.1000-6613.2015.09.028 Controllable reduction and characterization of graphene oxide ZHAO Jing ，ZHANG Hong （College of Chemistry and Chemical Engineering，Shanghai University of Engineering Science，Shanghai 201620， China ） Abstract：Graphene oxide (GO) was prepared by modified Hummers ，the reduction of GO was developed by using chitosan (CS) ，which is nontoxic and environment-friendly as a “green” reducing agent. And the reduction degree of GO was controlled by the temperature and time of reaction. The RGO was characterized with Fourier transform infrared spectroscopy ，X-ray diffraction spectroscopy ， UV visible absorption spectroscopy ，and Raman spectroscopy. Analysis shows that the change of temperature could not effectively control the reduction degree of GO. In 50 ℃ low temperature environment ，the different reduction degrees of reduction graphene oxide could be obtained by controlling the reaction time ，this result lay the foundation for the study of nonlinear optical properties of different reduction degree RGO. Key words ：graphene oxide ；graphene ；controllab