ICP-MS 法测定管线钢中痕量砷、铅、锡、锑、铋.pdfVIP

ICP-MS 法测定管线钢中痕量砷、铅、锡、锑、铋 ·1 · ICP-MS 法测定管线钢中痕量砷、铅、锡、锑、铋 孙 娟 庞振兴 顾红琴 王贵玉 金 伟 杜士毅 （首钢股份公司迁安钢铁公司，河北迁安 064400 ） 摘 要 随着管线钢牌号的不断升级，纯净度越来越高，钢中有害元素（砷铅锡锑铋）含量控制日趋严格，化学湿 法及 ICP-AES 法无法满足现场对痕量检测的需求。电感耦合等离子体质谱（ICP-MS ）作为一种超痕量元素分析的 强有力技术，具有极低的检出限和较宽的线性动态范围，可以满足现场痕量检验的要求。钢中砷、铅、锡、锑、铋 的存在会对钢铁的性能产生重要的影响，因此测定其准确含量具有重要的意义。本文研究了ICP-MS 法测定管线钢 中痕量砷、铅、锡、锑、铋的分析方法、对样品溶解、仪器参数、干扰情况等进行了优化，并计算了方法检出限和 方法检测下限。 关键词 ICP-MS ，内标，检测下限，功率 Determination of Trace As, Pb, As, Sb, Bi in Pipe Line Steel by Inductively Coupled Plasma Mass Spectrometry Sun Juan, Pang Zhenxing, Gu Hongqin, Wang Guiyu, Jin Wei, Du Shiyi (Shougang Qian’an Iron ＆Steel Company, Qian’an 064400, China) Abstract With the continuous upgrading of pipeline steel grades, steel becomes more and more purer and the content of harmful elements(As,Pb,Sn,Sb,Bi) in steel is more and more stricted control.Chemical and ICP-AES method can not meet the demand for analysis in time. Inductively coupled plasma Mass spectrometry (ICP-MS) technology as a powerful ultra-trace elemental analysis,it has very low detection limits and wide linear dynamic range,can meet the requirements of ultra-trace elemental analysis. The element(As,Pb,Sn,Sb,Bi) will have a major impact to performance steel, and therefore accurate determination has important significance. This paper studies the ICP-MS method for the determination of trace analysis methods As,Pb,Sn,Sb,Bi in the steel.The dissolution of the sample, instrument parameters and the interference were optimized and we calculate the detection limit of the method and the method detection low limit. Key words ICP-MS, the internal standard, the detection limit, the power 钢中痕量砷、铅、锡、锑、铋会对钢铁的强度、力学性能产生重要的影响[1~2] 。生产工艺需严格控制其 含量，因而痕量砷铅锡