微波等离子炬原子发射光谱法测定蔬菜中微量锗-吉林农业大学学报.PDF

DOI :10.13327/j.j jlau.2005.01.020 吉林农业大学学报　2005, 27 (1):79 ～82, 91 Journal of J ilin Agricultural University 董洪霞, 赵晓松 , 孙安娜, 李明堂 (吉林农业大学资源与环境学院, 长春 130118) 　:采用HNO —H PO —H O 消解体系处理蔬菜样品, 建立了微 等离子炬原子发射光谱(MPT-AES) 3 3 4 2 2 测定蔬菜中微量锗的方法, 并对相关实验参数进行了优化。 结果表明:在微 功率80 W, 负高压800 V, 分析 线 长265.118 nm, 等离子体工作气(Ar)流量0.50 L/min, 载气(Ar)流量0.90 L/min 条件下测定蔬菜样品中锗 含量, 检出限28.70 ng/mL, 回收率92.77%～ 95.60%, 变异系数小于4.00%。 该方法具有操作简便、样品用量 少、检出限低、灵敏度高、气体能耗少等优点。 :微 等离子炬原子发射光谱法;锗;蔬菜 :X12;X503.23　　　:A　　　:1000-5684(2005)01-0079-04 Determination of Germanium in Vegetable by Microwave Plasma Torch Atomic Emission Spectroscopy(MPT-AES) DONG Hong-ia, ZHAO Xiao-song, SUN An-na, LI Ming-tang (College of Resources and Environmental Science, J ilin Agricultura l University , Changchun 130118, China ) Abstract:A new method, microwave plasma torch atomic emission spectroscopy (MPT-AES),was used to determine trace elements germanium in vegetable and soil.The samples were wet ashed and then dis- solved by hydrochloric acid.Some e perimental parameters are discussed and optimized.Microwave power is 80 W, negative high pressure is 800 V, wavelength is 265.118 nm, support gas is 0.50 L/min, carri- er gas is 0.90 L/min.The recoveries are in the range of 92.77 %～95.60%and the RSD is less than 4.00%.The merits of the method are high sensitivity, rapidity, less sample quantity and so on. Key words:microwave plasma torch atomic emission spectroscopy;germanium;vegetable 　　 [3] [4] 、 、 [1]