吩嗪-5,10-二氮氧化物的合成及光谱性质的研究.pdfVIP

Advances in Analytical Chemistry 分析化学进展, 2014, 4, 34-40 Published Online August 2014 in Hans. /journal/aac /10.12677/aac.2014.43006 Determination Fluorescence Emission Spectra of Phenazine 5,10-Dioxide Using Multi-Peaks Gaussian Fitting Method in Different Solvent 1 1 2 2 Qiong Liu , Mingqiao Zhao , Changwei Xu , Jianhua Zhang 1 Guangdong Testing Institute of Product Quality Supervision, Shunde 2 School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou Email: zjhbox190@ st th th Received: Jul. 1 , 2014; revised: Jul. 14 , 2014; accepted: Jul. 25 , 2014 Copyright © 2014 by authors and Hans Publishers Inc. This work is licensed under the Creative Commons Attribution International License (CC BY). /licenses/by/4.0/ Abstract Phenazine 5,10-dioxide has been synthesized by a reaction of phenazine with hydrogen peroxide (H O ) in acetic acid (HAc) solution. And its fluorescence emission spectra has been determined in 2 2 different solvent by overlap peaks of a principal peak with a wavelength (λ) at 520 - 545 nm and a shoulder peak with λ at 500 - 515 nm, which are respectively assigned to dimer and monomer emission peaks. The maximum wavelength, peak area, and other spectral parameters for phena- zine 5,10-dioxide dimer and monomer were obtained from the analysis of overlap peaks by a mul- ti-peaks Gaussian fitting method, then the value of relative integral emission intensity for dimer and monomer (I /I ) in different solvents with various concentration can be obtained. When the 2 1 concentration of phenazine 5,10-di