手性选择性阳离子交换膜的制备及其评价-高校化学工程学报.PDFVIP

21 2 No.2 Vol.21 2007 4 Journal of Chemical Engineering of Chinese Universities Apr . 2007 1003-9015(2007)02-0206-05 , , , ( , 100084) (PVA) β (β-cyclodextrinβ-CD)(PAA) (chiral selective cation-exchange membrane, CSCM) DL-(DL-4-hydroxyphenylglycineDL-HPG) D- 1.21 1.34 β (cation-exchange membrane, CM)β β O648.22 TQ425.236 A Preparation and Evaluation of Chiral Selective Cation-Exchange Membranes FU Chun-jiang, WANG Jun, YU Li-xin, ZHU Shen-lin (State Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China) Abstract: Chiral selective cation-exchange membranes were prepared by blending poly (vinyl alcohol) as basic material, β-cyclodextrin as chiral selector and polyacrylic acid as ion-exchange material. Electrodialysis process for the separation of DL-4-hydroxyphenylglycine racemic mixture was carried out to evaluate these chiral selective cation-exchange membranes. Results show that D-4-hydroxyphenylglycine is preferentially transported through the chiral selective cation-exchange membranes in acidic medium. The selective factors of two kinds of chiral selective cation-exchange membranes are 1.21 and 1.34, respectively. As comparison, electrodialysis experiments using conventional cation-exchange membranes with or without adding β-cyclodextrin in feed were explored. These experiments verify that the chiral selectivity of chiral selective cation-exchange membranes originates from β-cyclodextrin. Key words: chiral selective; cation-exchange membrane; β-cyclode