洪春雁潘才元.PPT

－The End－ Thank You！ The excellent film-forming and unique encapsulation properties of many dendritic molecules can be combined to create multicolor, single-layer devices. Here, naphthyl dipheylamine terminated poly(benzyl ether) dendrimers with a coumarin laser dye or a pentathiophene core was used to prepare two-component (i.e. two-color), single layer devices. The dendrimers act as both hole transporters and emitters. Although a mixture of the two dyes only emitted light from the lowest band gap pentathiophene chromophore, dendritic encapsulation enabled simultaneous emissions from the two dyes. * A dendrimer can act as a support, displaying multiple copies of the catalyst at its periphery. In another approach, catalysis occurs within the dendrimer, offering possibities of encapsulation of the reactive site to avoid its deactivation, or the creation of a special nanoenvironment that assists and enhances the catalytic process. Here are 2 different representations of the same “reactor”. The amphiphilic design of the dendrimer catalyst leads to preferential accumulation of substrates and, in some instances, stabilization of transition states or intermediates in the interior, while the product is simultaneously expelled into the external medium, thereby preventing inhibition of the reactive site. * The researchers made the wires by attaching electrically-conductive molecules to the bases of branched polymers. Polymers are long, chain-like molecules that can easily be made to change shape. When the wedge-shaped dendrimers come together, they form cylinders around the conductive molecules attached to the points of the dendrimer wedges. The conductive molecules stack up, forming sets of four, five or seven columns encased within the dendrimer spiral. The dendrimers electrically insulate and keep moisture away from the electrically-conductive columns. The method could be used with many kinds of conductive materials, said Percec. A large variety of electronica