聚乙烯醇水凝胶自修复性能研究开发.PDFVIP

化 工 进 展 2016 年第35 卷第8 期 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·2507 · 研究开发 聚乙烯醇水凝胶自修复性能 龚桂胜，刘景勃，钟玉鹏，林强，张发爱 （桂林理工大学材料科学与工程学院，广西桂林541004 ） 摘要：高浓度聚乙烯醇（PVA ）水凝胶具有一定的修复功能，但其自修复机理及制备工艺参数对其修复性能的影 响缺乏研究。本文采用冷冻-解冻法制备了高浓度自修复PVA 水凝胶，通过调整PVA 水凝胶制备工艺参数（PVA 分子量、PVA 浓度、冷冻时间、解冻时间、冷冻-解冻次数、修复时间、冷冻温度等）得到了最佳工艺条件，分 析了水凝胶自修复机理，并研究了PVA 水凝胶的多次自修复性能。研究结果表明：相对分子质量大的PVA 制备 的水凝胶自修复性能好；其中冷冻时间为2h ，解冻时间为1h，一次冷冻-解冻循环制备得到的水凝胶自修复性能 最好，最佳修复时间为12h，能较好地进行反复自修复。指出水凝胶自修复性能主要是由其内部可逆氢键的相互 作用形成的，其主要影响源于冷冻-解冻处理后水凝胶内部羟基含量及PVA 分子的流动性。 关键词：聚乙烯醇；自修复；水凝胶；制备；机理 中图分类号：O 643 文献标志码：A 文章编号：1000 –6613 （2016 ）08 –2507 –06 DOI ：10.16085/j.issn.1000-6613.2016.08.31 Self-healing performance of poly(vinyl alcohol) hydrogel GONG Guisheng ，LIU Jingbo ，ZHONG Yupeng ，LIN Qiang ，ZHANG Faai （College of Materials Science and Engineering，Guilin University of Technology，Guilin 541004，Guangxi，China ） Abstract ：The high concentration of poly(vinyl alcohol) hydrogels possesses self-healing property. However ，its self-healing mechanism and the effects of the preparation conditions on the self-healing property of the hydrogel were rarely studied. In this paper ，the high concentration PVA hydrogel was prepared by the freezing and thawing method. The optimum conditions were obtained by changing the preparation conditions （the PVA molecular weight ，PVA concentration ，freezing time，thawing time ， numbers of freezing and thawing cycles ，healing time ，freezing temperature，etc. ） and the self-healing mechanism was analyzed. The multiple self-healing performance of the hydrogel was also investigated. The results showed that the larger the molecular weight of the PVA，the better