生物质热解动力学的研究-林产化学与工业.PDFVIP

23 4 Vo . 23 No. 4 200 3 12 Chem istry and Industry of For est Pr oducts Dec. 200 3 蒋剑春, 沈兆邦 ( 中国林业科学研究院林产化学工业研究所, 江苏 南京2 10042) J IAN G J C : : 4 . 2 40 / min , T GDSCT , , 390 , 4 . 2 / min , , 40 / min , 385 ~ 490 , ; 490~ 700 , , 29. 53 kJ/ mo , ( 70 ~ 110 kJ/ mo ) 10 20 / min , T GDSCT , , , , : ; ; : T Q 35 1. 2 : A : 0253- 2417( 2003) 04- 0001- 06 ST U DY ON REACT ION K IN ET ICS O F BIOMASS PY RO LY SIS J IA N G Jianchun, SHEN Zhaobang (Institute of Chemical Industry of Forest Products, CAF, N anj ing 210042, China) Abstract: T his paper dea s w it h the test resu ts of the study on the reaction kinetics of saw dust pyro ysis . U nder the condition of diff erent temperature rising rate, the reaction mechanism and process of biomass pyro ysis are changed. F or temperature rising rate of 4 . 2 and 40 / min, both T GDSCT curv es ar e simi ar in their endotherma peaks. F or temper ature r ising rate of 4 . 2 / min over 390 , chemica reaction kinetics can not be ex pressed by traditiona mathematica mode and the reaction rate appears to be in a inear re ation w ith reaction temperatur e. F or heating r ate of 40 / min w ithin the scope of turning points( at 385- 490 ) the reaction kinetics a so can not be ex pr essed w ith the mathematica mo de formu a used usua y. How ev er for r eaction temperatur e in the scope of 490 - 700 , t he reaction kinetics can be ex pressed by mathemat ica mode w it h very good corre ation of ine