石化工场高铬镍离心铸造炉管高温潜变破裂行为探讨.pdfVIP

石化工場高鉻鎳離心鑄造爐管高溫潛變破裂行為探討 防蝕工程　第二十三卷第三期　第175 ～ 182 頁　2009 年9 月 Journal of Chinese Corrosion Engineering, Vol. 23, No. 3, pp. 175 ~ 182 (2009) 蘇俊吉* 、陳孟宏、許峰彰 Creep Behavior of a Ruptured High Cr-Ni Centrifugal Casting Furnace Tube in a Petrochemical Plant Chun-Chi Su*, Meng-Hung Chen, Frank F. Sheu Received 25 August 2008; received in revised form 14 April 2009; accepted 6 May 2009 本研究主要藉由一使用 6 年之高鉻鎳離心鑄造爐管破裂的破損分析，來探討此類材料 之潛變破裂特性以及影響因素，同時從操作條件和鑄造品質來討論對爐管壽命的影響，破 裂爐管材質為HP-40 Mod Nb Micro alloy ，爐管外徑為125.6 mm ，壁厚為9 mm ，內容物組 成主要為合成氣、H 、CO 和CO ，內容物溫度為875 °C ，操作壓力為20 bar ，煙道氣溫度 2 2 平均為 1050 °C ，分析結果顯示爐管存在晶界孔洞、串聯孔洞和裂紋，以及沿晶破裂型態等 特徵，研判爐管破裂機制為潛變破裂，而過熱以及材料存在鑄造瑕疵是爐管潛變破裂的肇 因；塊狀的共晶碳化物提供更短的路徑，會加速潛變裂紋的成長速率；此外利用LMP 曲線 計算不同壁厚位置潛變壽命損傷比的結果和實際爐管截面之潛變裂紋分佈特徵吻合。 關鍵詞：離心鑄造；爐管；潛變；HP-40 Mod 。 ABSTRACT Creep behavior and the pertinent causes of a high Cr-Ni centrifugal casting furnace tube ruptured after a six-year service were investigated by failure analyses. The effects of operating parameters and casting quality on the creep life of the tube were discussed. The material of the ruptured tube is HP-40 Mod Nb micro-alloy. The outside diameter of the tube is 125.6 mm and the wall thickness is 9 mm. The operating temperature and pressure were 875 °C and 20 bar, respectively. The average flue gas temperature was 1050 °C. The