铁钛双金属掺杂SBA15的合成与表征.pdfVIP

铁钛双金属掺杂SBA-15 的合成与表征 * 李年凯，陈丹丹，孔岩，王军 （南京工业大学材料化学工程国家重点实验室，江苏南京 210009） 摘要：以正硅酸乙酯为硅源，硝酸铁和钛酸正丁酯为金属源，P123 为模板剂，采用直接水热合成法合成了 铁钛双金属同时掺杂的SBA-15 介孔材料。通过ICP、XRD 、BET 、FT-IR 等技术对材料的结构和性质进行 了表征。结果表明合成的材料具有典型的六方介孔结构，金属Fe 、Ti 可能存在于SBA-15 骨架中；双金属 之间存在相互影响，Ti 的引入可使Fe 的引入更容易；该材料用于苯乙烯过氧化氢氧化反应，较之单金属掺 杂环氧产物选择性有一定提高。 关键词：铁钛双金属；掺杂；SBA-15 中图分类号：O614.81+2 Synthesis and Characterization of SBA-15 Doped with Bimetallic Iron and Titanium * LI Niankai ，CHEN Dandan，KONG Yan ，WANG Jun (State Key Laboratory of Materials-oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, Jiangsu, China) Abstract ：A series of bimetallic Fe-Ti modified SBA-15 with different amount of iron and titanium was synthesized by direct hydrothermal method using ethyl orthosilicate , ferric nitrate, tetrabutyl titanate as silicon, iron, titanium source respectively, and P123 as template. The samples were characterized by using ICP-AES, XRD, FT-IR, and N2 adsorption-desorption isotherm techniques. The results revealed that all the samples exhibited an ordered hexagonal mesoporous structure. The atoms of iron and titanium were probably incorporated into the framework of 3+ 4+ SBA-15. Moreover, there was an interaction between bimetallic Fe and Ti , and the 4+ 3+ incorporation of Ti could increase the amount of Fe in SBA-15. In addition, the materials were used in the oxidation of styrene with hydroperoxide, and the selectivity of epoxide increased slightly than Fe-SBA-15