微波作用下聚羧酸系高效减水剂的合成及其性能研究 Synthesis and its performance of polycarboxylic superplasticizer under microwave-irradiation.pdfVIP

NUiq 新癯。壶巍豁拇 全国中文核心期刊 微波作用下聚羧酸系高效蹴7．1C,,LIDa 舍成及其Ⅱ生链研穷 张林1，李彦青：，李利军2蔡卓3，孑L红星2 (1．声西工学院￡木建筑[程系，广西柳州545006； 2．广询工学院生物与化学工程系，广西柳州545006； 3．广西大学化学与化工学院，广西南宁530004) 摘要：在微波作用下，以聚乙=醇一1000、丙烯酸和甲摹丙烯磺酸钠为丰要原料合成聚羧酸减水剂，通过单因素试验，得出了最 佳合成条件，而且整个工艺周期仅为3．5h，与现有工艺相比效率显著提高，充分显示了微波作用在合成中的优势。该工艺合成的聚 羧酸减水剂在掺量为0．5％、0．75％和1．O％时，砂浆减水率分别达到31．5％、41．1％及44．8％。 关键词：聚羧酸岛效减水剂；微波辐射：减水率 中图分类号：TU582．042．2文献标识码：A 文章编号：Z001—702X(2010)09—0045-04 and its of undermicrowave-irradiation Synthesisperformancepolycarboxylic superplasticizer ZHANGLinu,u I Zhu03,KONG Yanqin92，LILqun2，CA Hongxin92 (1．CivilConstruction of EngineeringDepartment，GuangxiUniversityTechnology。L／uzhou545006，Guangxi·China： of andChemical of 2．DepartmentBiologieal Engineering，GuangxiUniversityTechnology，Liuzhou545006，Guangxi·China； 3．Schoolof andChemical Chemistry Engineering，GuangxiUniversity，Nanning530004，Guangxi，China) Abstract：The with acidandsodium sulfonate polycarboxylicsuperplasticizerwa$synthesizedmacrogol1000，acrylic methallyl undermicrowave—irradiation conditionswereobtained 0．5％，0．75％and conditions．Optimum byMon—agentExperimentations．When 1．O％SAFWaSadded，thewaterreductionratewa陀31．5％，41．1％and44．8％．Thetimeofreactionlastedfor3．5hours，which only showedthatmicrowaveirradiationhadobviouseffecton thetime ofthe