界面学作业jidaan.docVIP

Problems and solutions Problems 1.List three materials containing interfaces and try to describe their structure. 2.What about the scale of polymer/polymer interfaces? 3.How to make a blends( presuming your two polymers are miscible ) ? 4.Describe UCST and LCST 5.How to find out if a blend is miscible or immiscible by measuring its Tg ? 6 Describe the function of graft copolymers of polystyrene grafted onto a polybutadiene backbone chain in HIPS 7Give the definitions : tensile strength; elongation; ultimate elongation; elastic elongation; tensile modulus toughness 8 What is the difference between toughness and strength? 9. Write your basic understanding of surface tension and surface energy 10.Write the equation to describe the relationship between the surface tensionand change in Helmholtz free energy 11List some techniques (at least 4) to determine the surface tension 12Give following definitions. work of adhesion；work of adhesion； roughness factor 13 Explain the meaning of following Fowkes equation. 14 Please sketch contact angle and explain it 15 Describe spreading coefficient and point out when a drop of a liquid could spread spontaneously over a solid in the absence of external force. 16 Calculate the spreading coefficient if the contact angle is 40?. What about the spreading coefficient if the contact angle increase to 60?? Indicate the correlation between the adhesive joint strength and contact angle(suppose contact angle 90 ?) 17 A convenient classification for adhesives is on the basis of mechanism by which the adhesives solidify, describe the classification of adhesives and give at least one example for each type. 18 A particular blend of polymers A and B has binodal points B1 and B2 at compositions containing volume fractions 0.20 and 0.85 of B．respectively．If a blend containing equal volumes of A and B is made，what fraction f of the total volume will be in phases corresponding to point B1 in equilibrium? 19 A polymer blend that obeys