硅烷化氟代聚丙烯酸酯乳液制备和其疏水性.pdfVIP

石 油 化 工 · 80 · PETROCHEMICALTECHNOL0GY 2011年第40卷第 1期 硅烷化氟代聚丙烯酸酯乳液的制备及其疏水性 亢玲娟，安秋凤，刘 爽，郝丽芬 (陕西科技大学 教育部轻化工助剂化学与技术重点实验室，陕西 西安 710021) [摘要]将 甲基丙烯酸十二氟庚酯、甲基丙烯酸十二醇酯、丙烯酸羟丙酯、甲基丙烯酸二甲氨乙酯和乙烯基三乙氧基硅烷在阳／非 离子复合乳化剂和引发剂过硫酸铵的作用下进行乳液聚合，制得了硅烷化氟代聚丙烯酸酯乳液(FLHDV)。用FTIR、SEM、XPS和 接触角测定仪分别对FLHDV的结构、成膜形态、膜表面的化学元素组成和疏水性进行了表征。表征结果显示，FLHDV具有 良好 的成膜性，硅氧烷的加入能增大FLHDV的交联度及其在涤纶纤维表面的结合牢度，赋予了涤纶织物优异的疏水性，使其由亲水 性织物转变为高疏水性织物 ，与水的接触角可达到 142．5。。 [关键词]氟代聚丙烯酸酯；硅烷改性；乳液聚合；疏水性；涤纶 [文章编号j1000—8144(2011)01—0080—05 [中图分类号]TQ314．24 [文献标识码]A Preparation andHydrophobieityofSilanizedFluoro-PolyacrylateEmulsion KangLingjuan，AnQiufeng，LiuShuang，HaoJLfien (KeyLaboratoryofAuxiliaryChemistryTechnologyforChemicalIndustry，MinistryofEducation ShaanxiUniversityofScienceTechnology．Xi’anShaanxi710021．China) [Abstract] Anovelsilanizedfluoro—polyacrylateemulsion(FLHDV)waspreparedbycopolymerization ofdodecafluoroheptylmethacrylate，laurylmethacrylate，2一hydroxypropylacrylate，dimethylaminoethyl methacrylateandvinyltrioxethylsiloxanewith(NH4)2S208asthewatersolubleinitiatorandcationic／ nonionicsurfactantsasthemixed emulsifier．The structure and thefilm morphology oftheprepraed FLHDV and the chemical composition and the hydrophobicity of the FLHDV film surface was characterizedby meansofFTIR．SEM ．XPS and the contactangle determination instrument．The resultsshowedthatthesmoothFLHDV film couldform ontheterylenesurface．Thesilanizationcould enhancethedegreeofcrosslinking ofthepreparedFLHDV anditsattachmenttotheterylene，which conferredexcellentwaterrepellencyonthetreatedterylene．Consequently，theterylenechanged from hydrophilicityto hydrophobicity，and itswater static contactangle on the treated terylene surface reached142．5。．