改性丙烯酸丁酯胶黏剂的制备 及性能研究.docVIP

本科学生毕业论文 的制备研究 黑 龙 江 工 程 学 院 二○一年六月  The Graduation Thesis for Bachelors Degree Preparation and performance of the modified butyl acrylate adhesive Candidate: Hao Daquan Specialty : Materials and Chemical Engineering Class : 08-2 Supervisor:Lecture Wang Xiaodan Heilongjiang Institute of Technology 2012-06·Harbin 摘 要 随着社会和经济的不断发展，无论从成本、可持续性还是，都对的要求越来越高。本研究课题从的成本、性能和可持续性，使用甲基丙烯酸丁酯为单体，采用聚合和两种合成方法，分别制得，最终确定其最佳工艺参数 实验证明，关键词；聚合；； ABSTRACT With the development of society and economy, regardless of cost, sustainable or green, the modified adhesive of the increasingly high demand. This research topic from butyl acrylate adhesive of cost, shear strength and sustainability, using butyl methacrylate as monomer, using emulsion polymerization and single, bicomponent acrylic polymer emulsion contact adhesive two synthesis methods, were prepared from modified acrylic glue adhesive, finally determines its best process parameters. The experiment proves, emulsion polymerization parameters: when the monomer amount20.00g, PVA amount of monomer mass 3%, initiator for0.5%, emulsifier for1.5%, waters monomer mass ratio is 6:1, Stirring speed control at 450 RPM / minute, reaction temperature of 75-80 ℃, reaction synthesis of 6h modified acrylate adhesive gel reaches above 16.73g. One-component and two-component adhesive emulsion process parameters : HEA and GMA as functional monomer, initiator dosage is 0.8, MS-1type emulsifier for acrylate monomer, the dosage is 2.5, reaction temperature 75 ℃. Key words: Modified adhesive; Emulsion polymerization; Contact adhesive emulsion; Shear strength;Butyl methacrylate 目 录 要 I Abstract II 第1章 绪 论 1 1.1本课题的选题背景 1 1.2研究目的及意义 1 1.3国内外研究现状 2 1.3.1国外研究现状 2 1.3.2国内研究现状 3 1.4丙烯酸酯胶黏剂的简介 3 1.4.1丙烯酸酯胶黏剂的发展 3 1.4.2丙烯酸酯胶黏剂分类 4 1.4.3改性丙烯酸酯胶黏剂的技术发展 4 1.4.4 物理性能的改性 4 1.4.5核壳型聚丙烯酸酯乳液胶黏剂性能及应用 5 1.5主要研究内容 6 第2章 丙烯酸丁酯的制备 7 2.1实验材料 7 2.1.1实验原料 7 2.1.2实验仪器 8 2.2 试验方法 8 2.2.1引发剂的处理 8 2.2.2丙烯腈（AN）的提纯 8 2.2.3甲基丙烯酸甲酯（MMA）的提纯 8 2.2.4乳液聚合法丙烯酸丁酯的合成 9 2.2.5乳液