水-乙醇体系对双极膜中间界面层的影响-化工学报.PDFVIP

第 67 卷 第 1 期 化 工 学 报 Vol.67 No.1 2016 年 1 月 CIESC Journal January 2016 水-乙醇体系对双极膜中间界面层的影响 刘小菏，李秋花，葛亮，徐铜文 （中国科学技术大学化学与材料科学学院，安徽合肥 230026 ） 摘要：选取Neosepta BP-1 ，Fumasep FBM ，CJ-BPM 三种商业标准双极膜作为研究对象，以水-乙醇为研究体系， 通过改变不同乙醇含量，测定双极膜的交流阻抗谱，并且对双极膜的耐溶剂性能进行评价，结果表明 BP-1 具有 良好的耐溶剂性，FBM ，CJ-BPM 耐溶剂性相对较弱；水解离现象发生在 LiCl 水-乙醇混合溶液中，随着乙醇含 量的增加，双极膜的阻值增加，而水解离程度降低。这种现象可以解释为醇解离能力要远远小于水解离能力，因 此乙醇的存在使得中间界面层区域的水浓度降低，进而降低了水解离程度；通过简化算法计算出了不同乙醇含量 下，BP-1 ，FBM 的中间界面层厚度，更直观地看出乙醇对双极膜水解离性能的影响。 关键词：水-乙醇体系；膜；离子交换；电化学；交流阻抗谱 DOI ：10.11949/j.issn.0438-1157 中图分类号：TQ 028.8 文献标志码：A 文章编号：0438—1157 （2016 ）01—0309—06 Influence of aqua-ethanol medium on properties of intermediate layer of a bipolar membrane LIU Xiaohe, LI Qiuhua, GE Liang, XU Tongwen (School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, Anhui, China) Abstract: A bipolar membrane (BPM) was composed of a cation and an anion ion-exchange layer joined together in series. The water dissociation in BPM was then considered as an electric field-enhanced (EFE) phenomenon and its magnitude depended critically on the structure and composition of the bipolar intermediate layer. By changing the different content of ethanol, three commercial bipolar membranes Neosepta BP-1, Fumasep FBM and CJ-BPM were tested by AC impedance spectra and their bipolar membrane solvent resistance were evaluated simultaneously. It was confirmed that BP-1 had good solvent resistance an