超级电容器论文：超级电容器不同孔结构分布的高比表面积活性炭电极材料的研究.docVIP

超级电容器论文：超级电容器不同孔结构分布的高比表面积活性炭电极材料的研究 【中文摘要】随着可再生能源和混合动力车（HEV）的日益发展,对轻巧型,紧凑型的电源的需求与日俱增。在储能电源之中,超级电容器由于拥有可弥补介电容器与传统电池差距的优良的功率输出性能,正受到人们广泛的关注。目前,超级电容器已广泛的应用到很多领域之中,包括便携式电子产品的能量储存和输出设备、电动车、可再生能源系统运行中的间歇电源。活性炭、过渡金属氧化物、导电聚合物等很多材料目前都被作为超级电容器电极材料的研究。活性炭由于其相对较低的成本,高的比表面积和良好的导电性,目前是超级电容器最广泛使用电极材料。因此,本文报道了一种简便、有效地途径合成拥有微孔-中孔结构的活性炭材料。活性炭的结构性质由热重分析,X射线衍射,氮气吸附/脱附等温线和透射电子显微镜等表征。结果显示,制备的活性炭的比表面积、微孔孔体积和中孔孔体积都得到了明显的提高。并且氢氧化钾、氯化锌、酚醛树脂三者的质量混合比例和活化温度对活性炭的孔隙率、比表面积和孔体积都有一个明显的影响。活性炭样品的电化学性能是在1 M Et3MeNBF4/PC有机电解液中调查。结果表明,经过调制得到的大量微孔在很大程度上提高了超级电容器的比电容,并且自由连接的中孔又进一步为离子的快速传输提供了渠道,还打开了被关闭的微孔,提高了微孔利用率。影响超级电容器电化学性能显著的微孔-中孔适中比率也被探究。在制得的一系列活性炭材料之中,由质量混合比为KOH/ZnCl2/PF = 1:2:2制备得到的样品PC-6在不同电流密度充放电的测试中显示了最优良的电化学性能。样品PC-6在有机电解液中表现出了142F/g的高比容量和36Wh/kg高能量密度。PC-6优良的电化学性能可归功于其发展优良的孔结构,高的比表面积,大的孔体积,还有平衡的微孔和中孔孔隙分布。 【英文摘要】With the growing development of renewable energy sources as well as hybrid electric vehicles （HEV）, the light-weight and compact electric power sources is supplying the increasing demand. Among them, supercapacitors have received much attention recently,because of their power delivery performance that perfectly fills the gap between dielectric capacitors and traditional batteries. Nowadays, supercapacitors have been widely used in many fields, including energy storage and power output technologies for portable electronics, electric vehicles, and renewable energy systems operated on intermittent sources. A variety of materials such as activated carbon, transition metal oxides and conducting polymers, etc, are currently investigated for use as electrode materials for supercapacitor. Activated carbons are the most widely used electrode material for supercapacitors because of their relatively low cost、high surface area and good electrical conductivity.In this study, we report a facile and efficient route to prepare a series of activated carbons, which have different micropore-mesopore architecture. Activated carbons are characterized by thermal gravimetric analysis, X-ray diffraction, nitrogen