驯化污泥系统论文：驯化污泥系统处理双酚A废水过程中污泥有机毒性分布规律研究.docVIP

驯化污泥系统论文：驯化污泥系统处理双酚A废水过程中污泥有机毒性分布规律研究 【中文摘要】剩余污泥的土地利用已经成为其重要的资源化方向,然而污泥的毒性积累已成为对后续资源化利用的最关键限制因素,基于这一问题,本试验在小试规模下,以处理疏水性毒性有机物双酚A(BPA)的活性污泥系统为对象,考察污泥有机毒性的形成过程及空间分布特性,为源头或后续消减有机毒性的资源化处理与处置提供理论指导。本试验用2.5mg/L的BPA模拟废水对SBR活性污泥系统驯化处理,随后驯化污泥运行阶段对BPA浓度分别为5mg/L.7.5mg/L.20mg/L40mg/L的模拟废水进行处理,同时监测各阶段浓度梯度出水COD,水相与泥相(外层胞外多聚物(EPS)和内层EPS+胞内)BPA浓度及毒性的变化趋势；单个周期内,水相COD、水泥两相BPA浓度及毒性随反应时间的变化趋势；探讨了空白组灭活污泥、空白组未灭活污泥和对照组未灭活污泥三种污泥对BPA吸附降解路径及毒性变化趋势。研究表明,驯化污泥对含BPA废水去除效果比未驯化污泥好,且经驯化的污泥所能承受的BPA废水浓度更高,主要体现为快速吸附后降解去除；在BPA降解过程中,外层EPS区域(占泥相体积百分数22.27%)没有BPA及毒性的积累;在驯化与运行过程中,驯化污泥内层EPS+胞内区域没有BPA残留,但毒性不断积累,这是因为BPA毒性降解产物或者BPA诱导微生物细胞分泌的毒性物质,滞留在内层EPS+胞内而引起。吸附与降解均可造成显著毒性,在每个运行周期末,对照组污泥系统毒性积累主要为有毒降解产物引起。 【英文摘要】Land utilization of excess sludge has become a vital way of resource recovery. However, the toxicity of sludge has become the most critical restriction for subsequent reuse. Base on this issue, Laboratory-scale batch experiments were conducted to investigate the formation process and spatial distribution characteristics of organic toxicity in acclimated sludge treating the hydrophobic toxic organic(BPA). to provide theoretical basis for the reduction of organic toxicity in situ or subsequent disposal.The reactor was operated in as SBR. acclimated with synthetic wastewater containing 2.5mg/L BPA. The influent concentration of BPA was 5mg/L.7.5mg/L.20mg/L and 40mg/L respectively. The effluent COD. concentration of BPA in water and solid phases(outer EPS and inner EPS+intracellular) and organic toxicity were analyzed in every stage. The effect of retention time on effluent COD. concentration of BPA in water and solid phases(outer EPS and inner EPS+intracellular) and organic toxicity in a single cycle were also analyzed. In addition, the variation of toxicity caused by adsorption or degradation in unacclimated inactivated sludge, unacclimated activated sludge and acclimated activated sludge were analyzed.The result showed that BPA removal efficiency of acclimated activated sludge is better than that of unac