DMA_Principle英文课件.pdfVIP

2005 Training School DMA Basic Principle s erma na ys s or Rheology Definitions Thermal Analysis is the measurement of some characteristic of a substance as a function of temperature or time. Rheology is the science of flow and deformation of matter. DMA is the general name given to an instrument that mechanically deforms a sample and measures the sample response. The deformation can be applied sinusoidally, in a constant (or step) fashion, or under a fixed rate. The response to the deformation can be monitored as a function of temperature or time. Rheology of Solids? Definition of Rheology The Science of flow and deformation of matter. mpor ance o o o ymer Rheology Polymeric materials are used extensively desirable mechanical properties economical cost For most applications, mechanical properties are considered the most important of all physical and chemical properties of polymers. Important facts when working with polymers Need to have some basic knowledge of the mechanical behavior Need to have an understanding of how the mechanical behavior can be modified by the numerous structural factors that can be varied ⇒ Rheology Nielsen, Lawrence E., Mechanical Properties of Polymers and Composites, Marcel Dekker, Inc., New York, 1974, p. 1. Polymers Exhibit Wide Range of Mechanical Strength A single polymer can exhibit an extremely wide range of mechanical behavior Very hard and rigid solid Stiff to Soft rubber Viscoelastic liquids The Mechanical strength of a polymer is a consequence of Chemical Composition of the Polymer Dictates where changes in mechanical properties occur Physical Molecular Structure of the Polymer Dictat