外加剂对混凝土TSA腐蚀抑制作用.pdfVIP

学兔兔 第33卷第2期 土 木 建 筑 与 环 境 工 程 V01．33 NO．2 2O11年 4月 Journal of Civil。Architectural 8L Environmental Engineering Apr．2011 外加剂对混凝土TSA腐蚀的抑制作用 杨长辉，班克成，刘本万 (重庆大学 材料科学与工程学院，重庆 400045) 摘 要：研究了掺加化学外加剂的水泥净浆试件在(5±2)℃、质量分数 5 的硫酸镁溶液中浸泡 300d的外观变化、强度发展及侵蚀产物，采用X射线衍射(XRD)、傅立叶转换红外光谱(FTIR)等 方法分析了侵蚀产物的组成。结果表明：甲酸钙能延缓水泥石发生TSA腐蚀，但不能阻止TSA发 生，在0．3％N0．7％范围内，随着甲酸钙掺量的增加，水泥石抗TSA腐蚀的能力增强。硝酸钡能有 效抑制水泥石中碳硫硅钙石的生成，原因是硝酸钡能结合生成碳硫硅钙石所需的SO ，从而降低 了水泥石发生TsA腐蚀的程度。硝酸钡掺量在 1 左右时，水泥石抗TSA性能较好。 关键词：化学腐蚀；化学外加剂；水泥净浆；碳硫硅钙石 中图分类号：TU528．042 文献标志码：A 文章编号：1674—4764(2011)02—0】26一O6 Inhibiting Effect of Admixtures on TSA of Concrete YANG Chang—hui，BAN Ke—cheng，LIU Ben—wan (Materials Science andEngineering School，Chongqing University，Chongqing 400045，China) Abstract：The cement paste added with chemical admixtures is kept out(5±2)℃，5 in mass MgSO4 corrosion solution in 300 d of immersion．Its visual appearance，compressive strength and erosion products are studied．Its erosion products are analyzed by the way of X—ray Diffraction (XRD)and Fourier Transform Infrared Spectroscopy(FTIR)．It shows that the calcium formate can delay the TSA of harden cement paste to occur，but can not stop the development of TSA． The resistance of mortar to TSA inereases with the raise of calcium formate in the range of 0．3 to 0．7 ．The reason why barium nitrate can inhibit the formation of thaumasite is that it can combine with SO。一 which is essentiai for the forming of thaumasite．Thus，the TSA of mortar is reduced in degree．The harden cement paste shows good resistance to TSA when barium nitrate is approximately 1 of cement． Key words：chemical atta