表面修饰纳米二硫化钼粒子的研制及极压性能.doc

表面( 田言 任南琪 冯玉杰 哈尔滨工业大学市政环境工程学院，哈尔滨150090，中国 [摘要]以十八烷氧基二硫代磷酸吡啶盐（PyDDP）为表面修饰剂，以钼酸钠、硫化钠、稀硫酸、盐酸羟胺为原料，合成了PyDDP修饰的MoS2纳米微粒。优化了还原过程、硫代过程和酸析出过程的工艺参数，采用IR、TG-DTA、UV、XRD等分析方法，对表面修饰纳米微粒进行了表征，并分析了表面修饰纳米二硫化钼微粒的形成机理。研究结果表明，所制备的微粒是一种表面为有机物修饰、且存在无机核的无机／有机纳米复合微粒。通过四球试验，研究了所制备微粒的摩擦学性能，并利用SEM、EDXA等方法对钢球表面的形貌、钢球表面元素进行了分析，探讨了所制备微粒对材料的摩擦学改善的机理。 [关键词]表面修饰；二硫化钼；极压抗磨剂；摩擦化学改性 [中文图书分类号]TH117.22 [文献标识码] A [文章编号] 1000-7857(2007) Preparation of Modified Nano-Molybdenum Bisulfide and Investigation on Their Properties at Extreme-pressure Condition Yan Tian, Nanqi Ren, Yujie Feng School of Municipal Environmental Engineering, Harbin Institute of Technology, Harbin 150090, China Abstract: Taking pyridine dialkyldithiophasphate(PyDDP) as surface modifying reagent, nano-molybdenum disulfide (MoS2) particles are synthesized with sodium molybdenum acid, sodium sulfide, sulfuric acid and hydroxylamine as raw materials. The technological parameters of the reduced process, sulfur replacement and separation process with acid are optimized. Infrared spectrum(IR), thermal gravity and differential thermal analysis(TG-DTA), X-ray diffraction(XRD), ultraviolet spectrum(UV) are employed to analysis the structure of nano-particles prepared. The modified mechanism of the surface modified nano- molybdenum disulfide is also investigated and results showed that the particles were built from a layer of organic material and a core of inorganic compound. The tribology properties of molybdenum bisulfide(MoS2) was evaluated with four-ball test method and the surface micrograph, elements composition are also obtained with SEM(Scan Electron Micrograph) and EDXA(Elctron Diffraction X-ray Analysis). It implied that the modified process could induce the materials better extreme properties. Keywords: surface modification; molybdenum bisulfide; anti-wear reagent at extreme pressure; modification with tribological chemistry CLC Number: TH117.22 Document Code: A Article ID: 1000-7857(2007) 0 引言 含钼极压抗磨剂是润滑油极压抗磨剂中重要的一类。