钢中铝_硅_锰复合脱氧反应的热力学计算.docxVIP

2011 年 9 月J o ur nal of Iro n a nd Steel Resea rchSep tember 2011钢中铝2硅2锰复合脱氧反应的热力学计算倪冰 ,刘浏 ,姚同路(钢铁研究总院冶金工艺所 , 北京 100083)摘 要 :复合脱氧后钢液的最终氧含量优于单独脱氧的效果 ,同时复合脱氧可产生低熔点 、易聚合长大的复合夹杂物 ,实现最佳的脱氧效果 。用热力学方法计算了铝2硅2锰复合脱氧的效果 ,结果表明 ,在不同硅锰比下 ,复合脱 氧均比单独用铝脱氧的最终氧含量要低 ;根据脱氧产物为锰铝榴石的原则得出了合金脱氧剂的组成成分 。热态试验验证了理论计算结果 。关键词 :铝2硅2锰合金 ;复合脱氧 ;热力学 ;夹杂物文献标志码 : A文章编号 :100120963 (2011) 0920008204Thermodyna mic Calculation Reaction Compound Deoxidat ion byAl2Si2Mn Alloy in Steel L iquidYA O To ng2l uN I Bi ng ,L IU L i u ,( Instit ute of Metall ur gical Technolo gy , Cent ral Iro n a nd Steel Re sea rch Instit ute , Beijing 100083 , China)Abstract : The final reactive o xygen co ntent in liquid steel by co mpo und deo xidatio n react w hich can p ro duce t he lo wmelti ng point a nd aggregated incl usio ns i s lo wer t ha n t hat by al uminum deo xidatio n react . Co mpo und deo xidatio n react by Al2Si2M n allo y wa s calculat ed acco r ding to t her mo dyna mic p rinciple. The re sult s i ndicate t hat t he final re2 active o xygen co ntent in liquid steel by Al2Si2M n deo xidatio n i s lo wer t ha n t hat by Al deo xidatio n. The co mpo nent of deo xidizing allo y i s calculated to o btain t he sp essa rtite . The calculatio n result in t heo r y wa s co nfir med by t he in2 cl usio n co mpo sitio n in steel sample by allo y deo xidatio n in a SiMo f ur nace.Key words :Al2Si2M n allo y ; dio xide ; t her mo dyna mic calculatio n ;incl usio nΔG°= - 1 202 000 + 3861 3 T[ 425 ][ Si ] + 2 [ O ] = SiO2 ( s)ΔG°= - 581 900 + 2211 8 T[ 425 ][ M n ] + [ O ] = M nO ( s)ΔG°= - 288 100 + 1281 3 T[ 425 ][ Si ] + 2 ( M nO) = 2 [ M n ] + ( SiO2 )ΔG°= - 5 700 - 341 8 T4 [ Al ] + 3 SiO2 ( s) = 2Al2 O3 ( s) + 3 [ Si ]ΔG°= - 658 300 + 1071 2 T2 [ Al ] + 3M nO ( s) = Al2 O3 ( s) + 3 [ M n ]ΔG°= - 320 600 + 1051 8 T2M nO ( s) + SiO2 ( s) = (2M nO ·SiO2 )ΔG°= - 53 555 + 241 73 T[ 6 ]3Al2 O3 ( s) + 2 SiO2 ( s) = (3Al2 O3 ·2 SiO2 )对钢液进行复合脱氧 ,使最终氧含量接近或者优于单独脱氧的效果[ 122 ] 。复合脱氧可产生低熔点 、 易碰撞长大的夹杂物 ,利于去除 Al2 O3