氮化硼基复合陶瓷型壳的抗钛液冲蚀能力-硅酸盐学报.PDFVIP

第37 卷第12 期 刘宏葆 等：氮化硼基复合陶瓷型壳抗钛液冲蚀能力 · 1957 · 第37 卷第12 期 硅 酸 盐 学 报 Vol. 37 ，No. 12 2 0 0 9 年 1 2 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY December ，2009 氮化硼基复合陶瓷型壳的抗钛液冲蚀能力 刘宏葆，毛协民，沈 彬，周 星 (上海大学材料与科学学院，上海 200072) 摘 要：研究了纯氮化硼型壳、氮化硼基复合型壳与熔融钛之间的界面反应，比较了2 种型壳的抵抗钛液冲蚀能力。对这2 种型壳的高温残余强度、 表面形貌、化学成分等进行了分析。结果表明：氮化硼基复合型壳中加入氧化钇，不仅能提高型壳的强度及致密度，还能在型壳内表层形成一层由均 匀随机分布的氧化钇和氮化硼粉粒网状链结成的“马赛克”结构的面层，具有显著提高型壳抗钛液冲刷和侵蚀的能力。 关键词：氮化硼；氧化钇；侵蚀；抗钛液冲蚀能力 中图分类号：TG146 ；TG249.5 文献标志码：A 文章编号：0454–5648(2009)12–1957–07 EROSION RESISTANCE OF BN-BASED CERAMIC COMPOSITE SHELL MOLD TO MOLTEN TITANIUM LIU Hongbao ，MAO Xieming ，SHEN Bin ，ZHOU Xing (School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China) Abstract: The reaction between molten titanium and two kinds of shell mold—pure boron nitride (BN) shell mold and BN-based ceramic composite shell mold were investigated. To compare the erosion resistance of different shell molds with molten titanium, the residual strength, the surface appearance and the chemical composition of those two kinds of shell molds were analyzed. The results show that the addition of yttria in the BN-based ceramic composite shell mold can not only increase the residual strength and the den- sity of the mold, but also make it possible for the formation of a compact surface layer with mosaic-like structure of yttria and BN parti- cles. The surface layer in BN-based shell mold can effectively improve the “inertness” of the shell mold to erosion of molten titanium. Key words: boron nitride; yttria; erosion; resistance of molten titanium 钛合金熔模精密铸造是钛合金成型的重要方法 生产成本的重要途径之一。 之一，是人们探索降