改性玉米淀粉的合成及其在印花糊料中的应用探究 Synthesis of modified corn starch and its application in printing paste.pdfVIP
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改性玉米淀粉的合成及其在印花糊料中的应用探究 Synthesis of modified corn starch and its application in printing paste
第 35 卷 第 7 期 染 整 技 术 Vol.35 No.7
2013 年 7 月 Textile Dyeing and Finishing Journal Jul. 2013
生产技术
改性玉米淀粉的合成及其在印花糊料中的应用探究
赵 扬,王 华,谭艳君
(西安工程大学 纺织与材料学院,陕西西安 710048)
摘 要 以玉米淀粉和氯乙酸为主要原料,乙醇为介质,采用有机溶剂的分步加碱法自制羧甲基淀粉(CMS)。
考察了原料配比、水用量、反应时间、反应温度等工艺条件对羧甲基淀粉(CMS)取代度、粘度等理化性能的影响,
确定了最佳的合成改性淀粉的工艺参数和试验方案。通过对羧甲基淀粉(CMS)粘度、流变性、印花得色量和
脱糊率等理化性能和印花效果的测试,发现其作为活性染料印花糊料具有假塑性好、稳定性高的优势,可以在
某种程度上取代海藻酸钠(SA)。
关键词 羧甲基淀粉(CMS);印花糊料;玉米淀粉
中图分类号:TS 194.2 文献标识码:A 文章编号:1005-9350(2013)07-0015-08
Synthesis of modified corn starch and its application in printing paste
ZHAO Yang, WANG Hua, TAN Yan-jun
′ ′
(College of Textiles and Materials Xian Polytechnic University, Xi an 710048, China)
Abstract Carboxymethyl starch (CMS) was prepared with corn starch and chloroacetic acid as main raw materials and
ethanol as medium through organic solvent alkali-feeding method step by step. Influences of raw material ratio, water
amount, reaction time and temperature on physical chemical properties of CMS such as substituting degree, viscosity etc.
were investigated. The optimal technological parameters and experimental scheme of preparing modified starch were also
optimized. CMS used as the printing thickner for reactive dyes was demonstrated good pseudoplasticity and high stability
merits by means of measureing viscosity, rheological property, printing color yield, paste removing rate and printing effect.
So CMS is able to replace sodium alginate to some extent.
Key words carboxymethyl starch;printing paste;corn starch
在活性染料的印花中,糊料一般用做增稠剂来 并通过单因素
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