液固反应中固体颗粒粒径变化规律的分析研究.pdf

液固反应中固体颗粒粒径变化规律的分析1 王慧青，周屈兰 （西安交通大学能源与动力工程学院，西安 710049） 摘要：通过盐酸消溶石灰石的实验，配合粒径测量系统，研究了粒径分布、反应温度、pH 值和搅拌速度对 石灰石活性的影响，同时还研究了石灰石颗粒粒径分布随反应时间的变化规律。结果表明：在实验测定的 范围内，温度越高、pH 值越低，越有利于石灰石的消溶；石灰石颗粒的平均粒径越小，石灰石的活性越高； 在搅拌器转速小于 300r/min 时，转速越高，石灰石消溶反应越快，当转速大于 300r/min，转速对石灰石 消溶反应基本无影响；随着反应的进行，石灰石颗粒的粒径分布逐渐向小粒径方向移动。 关键词：环境科学；石灰石；消溶率；粒径分布 中图分类号：X701. 3 文献标识码：A The Change of the Solid Particle Size Distribution in the Liquid-Solid Reaction WANG Huiqing, ZHOU Qulan (Xi’an Jiaotong University, School of Energy and Power, Xi’an, 710049, China) Abstract: By the experiment of limestone dissolution in hydrochloric acid solution, and using the measurement system of particle size to research the effects of particle size distribution, temperature, pH value, stirring speed. And also research the change of limestone particle size distribution with the reaction time. The result showed that: in the scope of the experiment, the higher temperature and the lower pH value are more conducive to the limestone dissolution. The smaller the average particle size is, the higher the activity of limestone is. When the stirring speed is less than 300r/min, the higher the speed is, the faster the limestone dissolution is. When the stirring speed is more than 300r/min, the stirring speed has no influence to the limestone dissolution. With the reaction of limestone dissolution, the particle size distribution of limestone particle is moving to the small particle size gradually. Keywords: environmental science; limestone; dissolution rate; partilce size distribution 我国电力工业以燃煤发电为主，燃煤发电量占全国总发电量的 70%左右。目前，燃煤 发电厂已成为我国大气SO [1] 2 污染的第一大污染源 。随着国家对环境保护的日益重视，关于 烟气脱硫技术的研究也开始被许多学者关注。由于湿法烟气脱硫(wet flue gas desulfurization, 简称 WFGD)是当今世界上普遍采用的主流技术，因此对其进行