基高强度高塑性高阻尼形状记忆合金研究.docVIP

锰基高强度高塑性高阻尼形状记忆合金研究 ? 机械研究与应用? 研夯与分析 锰基高强度高塑性高阻尼形状记忆合金研究 张瑞庆,缑顺虎,张艳红,张盛良,荆毅 (甘肃省机械科学研究院,甘肃兰州730030) 摘要:用磁悬浮熔炼,测定试样形状记忆效应(SME),金相法,DSC,断口SEM和自由震动波衰减曲线等研究了高强 度高塑性高阻尼的Mn基形状记忆合金的记忆特性,cu,Ni,Fe,cr,Ti,N等合金元素的作用.结果表明,cu溶 入愈多,合金的形状记忆效愈高;适当的时效热处理强化合金,提高SME;含Ti,N元素的合金Mn3有最好的 SME,回复率达73%.所研究的合金都有明显的双程形状记忆效应,合金Mn3的双程形状记忆效应达21%, 比较少见.淬火状态的合金有高的塑性,延伸率达25%,表示有极高的加工工艺性并有良好的阻尼抗震能 力.淬火时效状态的舍金有高的强度极限,尤其是高的屈服极限(or.=320—475MPa),适当的塑性(8=4.2— 5%以上),预示合金有较高的断裂韧性,断裂前会有明显变形预示,提高构件工作安全性.合金元素还能 提高所研究合金的抗氧化和抗腐蚀能力. 关键词:锰基高强度高塑性高阻尼记忆合金;形状记忆效应;形状回复率;时效热处理;合金元素 中图分类号:TG139.6文献标识码:A文章编号:1006—4414(2009)01—0017—05 mghstrenthhighplasticityhighdampingshapememoryalloysbasedonMn ZhangRui—qing,GouShun—hu,ZhangYan—hong,ZhangSheng—liang,JingYi (Gansuacademyofmechanicalsciences,LanzhouGansu730030,China) Abstract:HighstrengthhighplasticityhishdampingshapememoryalloysbasedonMn,containingelementsCu,Ni,Cr,Fe, Ti,Nandtheeffectsofalloyelementsonshapememorycharacterization,tensilepropertiesandtemperheattreatmenthave beeninvestigated,usingmagneticsuspensionmelting,determiningshapememoryeffect(SME),metallography,DSCofspeci- men,SEMoffracturesurfaceandfreedecaycurveofvibrationwave.TheresultsshowthatthemoreelementCuenterMn bulk,themoreshapememoryeffect(SME)is;temperheattreatmentimprovestheSMEoftestedalloys,butraisesthemar- tensitetransformationtemperature;alloyMn3,containingelementsTiandNpossessesthebestSMEamongthem,theshape recoveryrateisupto73%oAⅡthetestedalloyshaveexellenttwo—waySME,thetow—waySMEofalloyMIl3isupto 21%,itisnotwellkno,m.Alloyinquenchingstatehavehighplasticity,goodworkabilityoAlloysinquenbhingandtempe- ringstatehavehigherstrength,especiallyhighyieldstrength(or.=320~475MPa)andsuitableplasticity(6≥4.2—5%),SO shouldhavehigherfracturetoughnessKandhigherworksafety.Testedalloyspossessgooddampingabilityandgoodanti— oxidationandresistantcorrosion. Keywords:highstrengthhighplasticityhighdampingshapememoryalloysbasedonMn;shapememoryeffect(SME),shape recoveryrate;temperheattreatment;alloyelements 1前言 Mn基合金,主要是Mn—Cu系