内聚营养源SRB固定化交联剂的选择及对含锌废水的-中南大学学报.PDFVIP

第 39 卷第 2 期 中南大学学报自然科学版( ) Vol.39 No.2 2008 年 4 月 J. Cent. South Univ. (Science and Technology) Apr. 2008 内聚营养源SRB 固定化交联剂的选择及对含锌废水的处理 王 娜，闵小波，王云燕，周 敏，柴立元 ( 中南大学 冶金科学与工程学院，湖南 长沙，410083) 摘 要：以聚乙烯醇为包埋介质，对硫酸盐还原菌(SRB)进行固定化处理；以含锌废水为处理对象，考察不同交 联剂对成球性能影响、营养源内聚效果、硫酸盐还原效果、锌离子去除率和出水 COD(化学需氧量)等因素。研究 结果表明：最佳交联剂为 40% (NH ) SO 和 2% CaCl ；采用该交联体系制得固定化小球，每克小球内聚33.11 mg 4 2 4 2 乳酸钠，硫酸根还原率为 53.5%，锌离子去除率可达到 98%，出水 COD 低于 100 mg/L；固定化小球经过4 次循 环试验，出水锌离子浓度仍达到污水综合排放二级标准。 关键词：硫酸盐还原菌(SRB) ；交联剂；含锌废水 中图分类号：X703.1 文献标识码：A 文章编号：1672-7207(2008)02−0273−06 Determination of crosslinking agent in immobilized beads of SRB sludge with inner cohesive carbon source and treatment of wastewater containing zinc WANG Na, MIN Xiao-bo, WANG Yun-yan, ZHOU Min, CHAI Li-yuan (School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China) Abstract: The sulfate-reducing-bacteria (SRB) were immobilized in polyvinyl alcohol (PVA) to treat wastewater containing zinc. The effects of different crosslinking reagents on the conglobation, cohered efficiency of the carbon source, reduction ratio of sulfate, removal ratio of Zn( Ⅱ), and COD(chemical oxygen demand) of drainage were considered. The results show that the optimum crosslinking agents is 40% (NH ) SO and 2% CaCl , the content of 4 2 4 2 cohered lactate with immobilized beads cross linked by this agent is