含醇溶液的热力学研究-上海有机化学研究所.PDFVIP

2003 年第 61 卷 化 学 学 报 Vol. 61 , 2003 第 4 期 , 531～535 ACTA CHIMICA SINICA No. 4 , 531 ～535 含醇溶液的热力学研究 Ⅱ. 醇的水溶液的超额焓 沈晓燕　　章丽辉　　黑恩成　　刘国杰 (华东理工大学化学系 　上海 200237) 摘要 　提出了一个醇与水混和的热力学模型 ,它由三步组成 ,分别考虑了醇与水的物理混合 ,醇和水的自缔合破坏以及它 们间的交叉缔合. 据此建立了一个超额焓方程. 检验的结果表明 ,它能满意地描述含醇水溶液的超额焓随组成和温度的变 化规律. 含醇水溶液 ,超额焓 ,热力学模型 ,缔合 关键词 　 Study on Thermodynamics of Solutions Containing Alcohol Ⅱ. Excess Enthalpy for Aqueous Solutions of Alcohol SHEN , XiaoYan 　　ZHANG, LiHui 　　HEI , EnCheng 　　LIU , GuoJie ( ) Department of Chemistry , East China University of Science and Technology , Shanghai 20023 7 Abstract 　A thermodynamic model of the formation of aqueous solutions of alcohol is proposed. It is composed of three steps which take account of physical mixing , destructions of selfassociation and crossassociation for alcohol and water , respectively. An excess enthalpy equation is established based on this thermodynamic model. The results of test show that the equation can be satisfactorily used to describe the rule of variation of excess enthalpy with composition and temperature for aqueous solutions of alcohol. Keywords 　aqueous solution of alcohol , excess enthalpy , thermodynamic model , association 　　在含醇溶液的热力学研究中 ,醇的水溶液的超额焓研 完成 : 究占有特殊的地位. 这是由于醇与水都是强缔合物质 ,它们 第①步是醇的缔合液体与水的缔合液体物理混合 ,变成 间会发生强烈的作用 ,是一类典型的非理想