腰果酚酚醛环氧树脂的合成与表征-林产化学与工业.PDFVIP

腰果酚酚醛环氧树脂的合成与表征 * 霍淑平,孔振武 ,陈健,吴国民,刘贵锋 (中国林业科学研究院林产化学工业研究所;生物质化学利用国家工程实验室;国家林业局林产 化学工程重点开放性实验室;江苏省生物质能源与材料重点实验室, 江苏 南京 210042) 摘摇 要:摇 以腰果酚为原料,通过合成腰果酚酚醛树脂,进而合成腰果酚酚醛环氧树脂(Epoxy-I)和 高环氧值的腰果酚酚醛环氧树脂(Epoxy-II),探讨了各阶段的反应条件。 其中腰果酚酚醛树脂合 HUO Shu鄄ping摇摇 成的最佳条件为:催化剂乙酸锌用量为腰果酚质量的3%,在90 益 下反应3h;Epoxy-I合成的最佳 条件为:苄基三乙基氯化铵(BTEAC)催化剂用量为2%,在90 益 下醚化反应4h;当环氧化剂用量为Epoxy-I 质量的 80%,在70 益 反应6h可制备出高环氧值的Epoxy-II。 采用傅里叶红外光谱和核磁共振光谱表征了两种目标环氧树脂 的化学结构。 关键词:摇 腰果酚;甲醛;酚醛环氧树脂 中图分类号:TQ351摇 摇 摇 摇 摇 摇 文献标识码:A摇 摇 摇 摇 摇 摇 文章编号:0253-2417(2012)06-0041-06 Synthesis and Characterization of Cardanol Novolac Epoxy Resin HUO Shu鄄ping,KONGZhen鄄wu,CHENJian,WU Guo鄄min,LIU Gui鄄feng (Instituteof Chemical Industry of Forest Products,CAF;National Engineering Lab.for Biomass Chemical Utilization;Key and Open Lab.of Forest Chemical Engineering,SFA;Key Lab.of BiomassEnergy and Material,Jiangsu Province,Nanjing210042,China) Abstract:Cardanol novolac epoxy resin I (Epoxy鄄I) and cardanol novolac epoxy resin II (Epoxy鄄II) with higher epoxy value were synthesizedfromcardanol novolacresin synthesizedfromcardanolreactedwithformaldehyde. Theeffectsof variousreaction factors on these reactionswere investigated. The results showed that the optimal reaction conditionsfor the synthesis of cardanol novolac resin were asfollows:3% weight ratio of cardanol used as the amount of zinc acetate,the reaction temperature 90 益 and the reactiontime3h. Theoptimalreactionconditionsforthesynthesisof Epoxy鄄Iwerethattheamountof quaternary BTEAC was2 % weightratioof cardanolnovolacresin,thereactiontemperaturewas90 益 andthereactiontimewas4 h. Andtheepoxy value of Epoxy鄄II reaches to the highest when the amount of epoxidizing agent is 80% the weight ratio of Epoxy鄄I,the reaction temperature is70 益 andthereactiont