二氧化钌活性炭复合电极的制备及性能-中南大学学报.PDFVIP

42 2 () Vol.42 No.2 2011 2 Journal of Central South University (Science and Technology) Feb. 2011 ( 410083) RuCl ·2H O 3 2 / / /4 321.4 m2/g11.4 MPaH SO 0.5 mol/L20 mV/s 2 4 422 F/g0.33 Ω300 98.8% TM53 A 1672−7207(2011)02−0336−06 Preparation and performances of RuO /AC composite electrode materials 2 GAN Wei-ping, LIU Ji-yu, SHI Xiang, LIU Hong, LI Xiang, MA He-ran (School of Materials Science and Engineering, Central South University, Changsha 410083, China) Abstract: To research low-cost, high specific capacitance key composite electrode materials for super-capacitors, ruthenium oxide coated active carbon (RuO2/AC) was prepared by coating and thermal decomposition of ruthenium chloride on AC matrix. The morphology of the composite electrode was investigated by SEM. The performances of RuO2/AC composite membrane electrode at different coating numbers were characterized by adhesion, cyclic voltammetry, constant current charge-discharge and electrochemical impedance spectroscopy analyses. The results show that the best coating number is 4 times, when the composite film has a surface area of 321.4 m2/g, and adhesion of 11.4 MPa. The specific capacitance of RuO /AC composite electrode is 422 F/g measured at 20 mV/s in 0.5 mol/L H SO , and 2 2 4 the inner resistance is 0.33 Ω. After 300 cyclic-life, the specific capacitance of RuO2/AC composite electrode is kept at 98.8%, i