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Engineering 3 (2017) 416–422 Contents lists available at ScienceDirect Engineering journal homepage: /locate/eng Research Green Chemical Engineering—Article Thermodynamic Analysis of the Gasification of Municipal Solid Waste Pengcheng Xu, Yong Jin, Yi Cheng* Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China a r t i c l e i n f o a b s t r a c t Article history: This work aims to understand the gasification performance of municipal solid waste (MSW) by means Received 1 December 2016 of thermodynamic analysis. Thermodynamic analysis is based on the assumption that the gasification Revised 12 March 2017 reactions take place at the thermodynamic equilibrium condition, without regard to the reactor and process Accepted 26 March 2017 characteristics. First, model components of MSW including food, green wastes, paper, textiles, rubber, Available online 11 May 2017 chlorine-free plastic, and polyvinyl chloride were chosen as the feedstock of a steam gasification process, with the steam temperature ranging from 973 K to 2273 K and the steam-to-MSW ratio (STMR) ranging from Keywords: 1 to 5. It was found that the effect of the STMR on the gasification performance was almost the same as that Gasification of the steam temperature. All the differ