不同形貌镍纳米粒子_石墨烯复合材料的制备及微波吸收性能.docx

[Article]doi:10.3866/PKU.WHXB201208292不同形貌镍纳米粒子-石墨烯复合材料的制备及微波吸收性能李松梅*王博刘建华于美安军伟(北京航空航天大学材料科学与工程学院,空天材料与服役教育部重点实验室,北京100191)摘要:采用原位化学还原方法制备出了两种不同形貌的镍纳米粒子-石墨烯(Ni-GNs)复合材料,并研究了形貌对复合材料电磁吸收性能的影响.制备过程中通过改变反应物的加入顺序,制备出球形和刺球形镍纳米粒子-石墨烯复合材料.利用X射线衍射(XRD)仪、扫描电子显微镜(SEM)、透射电子显微镜(TEM)和矢量网络分析仪(VNA)对复合材料的形貌、结构和微波吸收性能进行了表征.结果表明:刺球形镍纳米粒子-石墨烯复合材料相比于球形镍纳米粒子-石墨烯复合材料具有优异的电磁吸收性能,其原因是由于复合材料中刺球形镍纳米粒子独特的各向同性天线形貌引起的尖端放电效应.因此利用简单的原位化学还原制备不同形貌镍纳米粒子-石墨烯复合材料的方法可以作为其他复合材料制备的总体路线.关键词:石墨烯;镍;纳米复合材料;微波吸收;原位化学还原方法中图分类号:O641;TB333SynthesisandMicrowaveAbsorptionPropertiesofNickelNanoparticles-GrapheneCompositeswithDifferentMorphologiesLISong-Mei*WANGBoLIUJian-HuaYUMeiANJun-Wei(KeyLaboratoryofAerospaceMaterialsandPerformance,MinistryofEducation,SchoolofMaterialsScienceandEngineering,BeihangUniversity,Beijing100191,P.R.China)Abstract:Nickelnanoparticles-graphene(Ni-GNs)compositeswithtwodifferentmorphologiesweresuccessfullysynthesizedbyinsituchemicalreduction,andthemorphology-dependentelectromagneticabsorptionpropertiesofthecompositeswasinvestigated.Bychangingthesequenceofthereactantsareaddedduringpreparation,sphericalandspinoussphericalnickelnanoparticle-graphenecompositeswereobtained.Thestructure,morphology,andmicrowaveabsorptionpropertiesofthecompositeswerecharacterizedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM),transmissionelectronmicroscopy(TEM),andvectornetworkanalysis(VNA).Theresultsindicatedthatthespinoussphericalnickelnanoparticle-graphenecompositeshadbettermicrowaveabsorptionabilitythanthesphericalnickelnanoparticle-graphenecomposites.Thisisduetotheuniqueisotropicantennamorphologyofthespinoussphericalnickelnanoparticlesinthecomposites,arisingfromthepointdischargeeffect.Thisfacileinsituchemicalreductionmethodforthepreparationofnickelnanoparticle-graphenecompositestogivedifferentmorphologiescouldbeusedforthepreparationofothercomposites.KeyWords:Graphene;Nickel;Nanocomposite;Microwaveabsorption;In-situchemicalreductionmethodReceived:July2,2012;Revised:August27,2012;PublishedonWeb:August29,