葡萄糖作为碳源合成LiFePO4C正极材料的电化学性能研究.pdfVIP

葡萄糖作为碳源合成LiFePO /C正极材料的电化学性 4 能 唐致远 焦延峰 （天津大学化工学院应用化学系 天津 300072） 摘要:采用固相反应法在惰性气氛下合成了橄榄石型 LiFePO /C 正极材料，采用 XRD ，SEM 和电化学手段对 4 目标材料进行了结构表征和性能测试。考察了葡萄糖作为碳源对LiFePO4/C 正极材料性能的影响。结果表明， -1 以葡萄糖作为碳源的正极材料具有优良的电化学性能，首次放电比容量达 136.3 mA·h·g ，远远高于纯的 LiFePO4 正极材料，随着循环次数的增加，材料的放电容量逐渐增加然后趋于稳定。循环30次后，容量为 139.6 mA·h·g-1 。 关键词：碳源；葡萄糖；蔗糖；磷酸亚铁锂；橄榄石型；正极材料 The Performance of LiFePO /C Cathode Material with 4 Glucide as Carbon Source Tang zhi-yuan, Jiao yan-feng (Deparment of Applied Chemistry, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072) Abstract: Olivine LiFePO /C cathode material was synthesized by a solid state method 4 in an inert atmosphere. The crystal stucture and electrochemical performance were characterized by XRD, SEM and electrochemical performance testing. The effects of dextrose and sucrose as carbon source on the performance of LiFePO4/C cathode material were investigated and the causes also analyzed. The results demonstrated that the composite material carbon-doped by dextrose had the most excellent electrochemical performance. The initial discharge capacity of the sample as a lithium secondary battery was achieved to 136.3 mA·h·g-1, at 0.1C (corresponding to 17 mA·g-1), larger than that of the sample without carbon-doped. The discharge capacity of the material increased and th