聚酰胺PA聚偏氟乙烯PVDF中空纤维复合纳滤膜的研讨.pdfVIP

B102 聚酰胺(PA)/聚偏氟乙烯(PVDF)中空纤维复合纳滤膜 的研究 * 张耀 许振良 刘久清 （华东理工大学化学工程研究所，上海200237 ） 摘要：利用界面缩聚法制备聚酰胺(PA)/聚偏氟乙烯(PVDF) 中空纤维复合纳滤膜，研究了油、水相浓度配 比、溶质浓度、反应时间、添加剂的浓度、制备工艺、反应温度等对PA/PVDF 复合膜性能的影响，探讨 了不同工艺对PA/PVDF 复合纳滤膜制备的影响。实验结果表明，PA/PVDF 中空纤维复合纳滤膜对2‰ 的 Na SO 、MgSO 、MgCl 、KCl 、NaCl 、PEG600 、PEG1000 和十二烷基硫酸钠的截留率分别达到了92.3%、 2 4 4 2 75.1 %、7.0%、9.5%、14.2%、88.4%、89.3%和90.5%，通量为50L/m2 ·h·Mpa。此外，分析了PA/ PVDF 中空纤维复合纳滤膜结构。 关键词：界面缩聚；中空纤维纳滤膜；均苯三甲酰氯；哌嗪 中图分类号 TQ 028.8 Study on the Preparation of Polyamide/ Polyvinylidene Fluoride Hollow Fiber Composite Nanofiltration Membrane 1 ZHANG Yao , XU Zhen-Liang and LIU Jiu-Qing (Chemical Engineering Research Center, East China University of Sci. and Tech., Shanghai, 200237, P.R.China) Abstract Using interfacial polymerization, a novel polyamide (PA) composite nanofiltration membrane was prepared. The effects of ratio of solute concentration in two phases, reactive time, additive concentration, routes of preparation, reactive temperature on performance of composite nanofiltration membrane were systematically investigated. A new preparation route was specially discussed which contained an extra step, that was, merging support membrane into water phase again after a functional layer had been generated. The hollow fiber composite nanofiltration membrane prepared had good performance shown that the rejections of Na2SO4, MgSO4, MgCl2, KCl, NaCl, PEG600, PEG1000 and sodium dodecyl sulfate (SDS) were 92.3 %, 75.1 %, 7.0 %, 9.5 %, 14.2 %, 88.4 %, 89.3 % and 90.5 % respectively, and the pure water permeability were about 50 项目资助：国家经贸委技术创新计划（编号：01BK-221 ）。 第一作者：张耀(1979-),安徽, 硕士, 主