生物可吸收聚酯聚碳酸酯共聚物的合成及其结构性能研讨.pdfVIP

Bioresorbable School submittedtotheCommitt∞ofGraduate Dissertation in Fulfillmentofthe partiaI Requirements FortIleDegreeof DoCTORoFPHILoSoPHY Science矾d Materials Engineering Fud锄UniVe体时 October2009 by 2009 ◎CopyrightJi觚Y抽g All Reserved Rights 1．1．4有机催化开环聚合………………………………………………………………………．7． 1．1．5酶催化开环聚合…………………………………………………………………………．9． 1．2生物可降解形变记忆聚合物………………………………………………………………．．10． 1．2．1聚合物形变记忆的原理………………………………………………………………．．11． 1．2．2形变记忆的测试与模犁………………………………………………………………．．13． 1．2．3形变记忆的分子结构要求……………………………………………………………．．14． 1．2．4热致形变记忆聚合物…………………………………………………………………．．．15． 1．2．4．1玻璃化温度充当转变温度…………………………………………………………．．．15． 1．2．4．2结晶温度充当转变温度………………………………………………………………．16． 1．2．5光致形变记忆聚合物…………………………………………………………………．．16． 1．3聚合物的降解………………………………………………………………………………．．17． 13．1水降解…………………………………………………………………………………．．17． 1．3．1．1水降解机理……………………………………………………………………………．17． 1．3．1．2聚酯．聚碳酸酯共聚物的水降解……………………………………………………．．18． 1．3．2酶催化降解……………………………………………………………………………．．20． 1．3．2．1蛋白酶…………………………………………………………………………………………………………。．21． 1．3．2．2脂J畸酶…………………………………………………………………………………………………………。．21． 1．3．2．3聚酯和聚碳酸酯的酶降解…………………………………………………………．．．23． 1．4本论文课题的提出…………………………………………………………………………．．23． 参考文献…………………………………………………………………………………………．25． 第二章聚酯一聚碳酸酯共聚物的合成…………………………………………………………．．．38． 2．1实验部分……………………………………………………………………………………．．38． 2．1．1试剂与材料……………………………………………………………………………．．38． 2．1．2单体的制备……………………………………………………………………………．．38． 2．1．2．1D，L．丙交酯单体的制备………………………………………………………………．38． 2．1．2．2L广丙交酯单体的制备…………………………………………………………………．39． 2．1．2．3乙交酯单体的制备…………………………………………………………………．．．39． 2．1．2．4三亚甲基碳酸酯单体的制备………………………………………………………．．．40．