低温等离子体改性PAN+膜回收酮苯溶剂研究.pdfVIP

B017 低温等离子体改性 PAN 膜回收酮苯溶剂 陈剑 李继定 王鼎 赵之平 陈翠仙 清华大学化学工程系膜技术工程研究中心，北京，100084） （ 摘 要 采用低温等离子体接枝技术改性 PAN 膜，在 PAN 膜表面引入疏水性单体苯乙烯，达到 改变膜表面孔径大小的目的，从而将 PAN 超滤膜改性成纳滤级别的膜。通过傅立叶红外光谱 （FT-IR ）分析膜的表面结构变化，用差示扫描量热仪(DSC)分析接枝前后膜表面孔径的变化。 研究了等离子体照射功率、照射时间、接枝时间对膜分离性能的影响。考察了苯乙烯改性膜对润 滑油脱蜡溶剂（甲苯和丁酮）体系的分离性能，结果表明，采用接枝的 PAN 膜用来回收溶剂甲 苯丁酮效果良好，可使苯酮溶剂的含量由 83.94wt ％提高到 98.42wt ％，对润滑油的截留率达到 了90.2％。 关键词 聚丙烯腈 等离子体 溶剂回收 分类号:TQ028.8 文献标识码: A SURFACE - GRAFT MODIFICATION OF POLYACRYLONITRILE ( PAN) MEMBRANE BY LOW- TEMPERATURE PLASMA TO RECYCLE KETONE-BENZENE SOLVENT Jian Chen, Jiding Li, Ding Wang, Zhiping Zhao and Cuixian Chen (Department of Chemical Engineering, Tsinghua University, Beijing 10084, China) Abstract Low temperature plasma-induced grafting modifications of polyacrylonitrile (PAN) membrane were studied to prepare hydrophobic nanofiltration membranes. By argon (Ar) treating and subsequent grafting reaction, a hydrophobic monomer, styrene, was introduced onto PAN membrane. Fourier transform infrared attenuated total reflection (FTIR-ATR) spectrum and differential scanning calorimetry (DSC) were employed to characterize the chemical and physical changes of modified membranes. The effectiveness of modification was studied under different plasma operation variables and graft reaction conditions such as plasma power, plasma time, and treatment time. PAN membrane modified by low temperature plasma has been shown to have excellent chemical resistance and rejection characteristics for the separation of solvents from lube oil filtrates，i.e. for the feed composition of 83.94wt% solvent, the solvent in permeate solution was 98.42wt%, and the rejection of oil was 90.2%. Keywords Po